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Anhui Liwei Chemical Co., Limited.

Ateva 2842AC EVA Copolymer Resin,28% VA,400 MI,Hot Melt Adhesive Grade

    • Product Name: Ateva 2842AC EVA Copolymer Resin,28% VA,400 MI,Hot Melt Adhesive Grade
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co., Limited.
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    Specifications
    HS Code 312717
    Vinyl Acetate Content 28 wt%
    Melt Index 190 C 2 16 Kg 400 g/10 min
    Density 0.954 g/cm³
    Melting Point Dsc 67 °C
    Ring Ball Softening Point 96 °C
    Glass Transition Temperature -41 °C
    Tensile Strength At Break 5.0 MPa
    Elongation At Break 800 %
    Hardness Shore A 80
    Brittleness Temperature -50 °C
    Crystallinity 18 %
    Vicat Softening Point 54 °C

    As an accredited Ateva 2842AC EVA Copolymer Resin,28% VA,400 MI,Hot Melt Adhesive Grade factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied as free-flowing pellets in 25 kg multiwall paper bags, palletized and stretch-wrapped for safe transport and storage.
    Container Loading (20′ FCL) 20' FCL loaded with 25kg bags of Ateva 2842AC EVA resin, approximately 20 metric tons per container, secure and dry.
    Shipping Ateva 2842AC EVA resin is shipped as free-flowing pellets in moisture-protective 25 kg bags, octabins, or bulk sacks. Keep dry, away from direct sunlight, heat, and ignition sources. Standard non-hazardous handling applies; avoid dust accumulation. Ensure containers are sealed during transit to prevent contamination.
    Storage Store Ateva 2842AC EVA Copolymer Resin in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and open flames. Keep containers tightly sealed to prevent moisture absorption and contamination. Maintain moderate temperatures to avoid softening or agglomeration. Use FIFO rotation; protect from physical damage and store separately from incompatible materials.
    Shelf Life Store in a cool, dry area away from heat, sunlight, and moisture. Shelf life is one year from date of manufacture.
    Application of Ateva 2842AC EVA Copolymer Resin,28% VA,400 MI,Hot Melt Adhesive Grade

    On high-speed case erecting and packing lines running at 4560 cartons per minute, flap spring-back before the compression station remains a failure point tied to insufficient hot tack on clay-coated recycled linerboard. Ateva 2842AC, a 28% vinyl acetate copolymer with a melt mass-flow rate of 400 g/10 min at 190 °C/2.16 kg under ISO 1133-1:2022, is compounded at 3038 wt% with hydrogenated rosin ester tackifier at 3542 wt%, Fischer-Tropsch wax at 2028 wt%, and hindered phenolic antioxidant at 0.51.0 wt%. The first-stage batch mixer runs at 150170 °C jacket temperature under a nitrogen blanket to minimize oxidative gel formation; subsequent transfer through heated hose to an air-actuated slot nozzle is maintained at 150165 °C. On a case erector, adhesive add-on for top and bottom major flaps is typically 0.81.5 g/m per flap pair, with open time on recycled corrugated board at 812% moisture limited to 48 s. Set time under compression pressure of 0.10.3 MPa drops below 2 s, allowing immediate palletizing. Compliance for food packaging closure is covered by FDA 21 CFR 175.105 and EU Regulation EC No 1907/2006; REACH SVHC declarations are required for the tackifier and wax fractions. Terminal finished product types include single-wall and double-wall corrugated cases, die-cut mailers, litho-laminated folding cartons, and bag-in-box outer shells. The operational boundary is a bulk adhesive temperature above 180 °C: hold times exceeding 8 h at this temperature can generate char and gel particles that plug the nozzle and produce intermittent skip-bonding at line speeds above 60 m/min. These addition ratios are starting windows; compatibility with recycled board coatings and wax-grade changes must be validated on the production line because published adhesion data for coated linerboard is limited.

    Case and carton sealing hot melt formulation frame
    ComponentTypical additionProcess functionOverdose/underdose failure mode
    Ateva 2842AC30–38 wt%Cohesive strength, wet-out on clay-coated linerboardOverdose raises open time and stringing; underdose lowers peel adhesion
    Hydrogenated rosin ester tackifier35–42 wt%Adhesion to recycled board and mineral coatingsOverdose increases tackifier bleed; underdose reduces hot tack
    Fischer-Tropsch wax20–28 wt%Set speed, viscosity reductionOverdose causes cold flex cracking; underdose extends compression time
    Hindered phenolic antioxidant0.5–1.0 wt%Thermal stabilization during hold timeOverdose can migrate to surface; underdose increases gel formation

    What Governs Spiral Spray Transfer in Multiline Nonwoven Lamination?

    In disposable hygiene converting, continuous film application would compromise breathability and hand feel; the adhesive is therefore delivered as a spiral-spray pattern from a slot die. Ateva 2842AC at 2028 wt% of the hot melt provides the low-viscosity backbone because its 400 g/10 min melt index permits fiber elongation under nozzle air pressure of 0.060.12 MPa without excessive film tearing. The compounded formulation is held at 138152 °C in a melt reservoir, filtered through a 100200 μm screen, and dispensed through solenoid air-open modules across a web speed of 300600 m/min. Add-on is controlled in the range 1.53.5 g/m² per spiral line, because below 1.0 g/m² bond strength falls sharply on polyethylene backsheet and above 4.5 g/m² squeeze-through and stiff spots appear. Compliance rests on REACH EC No 1907/2006 and, where the finished article is classified as a medical device, EN ISO 10993-5 and 10993-10 cytotoxicity and skin irritation assessments. Some converters also require absence of rosin ester and methacrylate sensitizers in the formulation. Terminal finished product types include infant diaper elastic attachment, adult incontinence core stabilization, feminine hygiene cuff and acquisition layer bonding, and disposable underpads. The primary production bottleneck is nozzle degradation from high adhesive temperature; hold times above 8 h at 150 °C can increase char formation and produce spiral pattern breakdown.

    Where Low-Temperature Flex Cracking Limits Unsewn Book Block Adhesion

    Perfect binding lines cycling at 8,00012,000 books per hour impose two adhesive requirements: rapid set for the spine glue and retained flexibility in the hinge after trimming and cooling. Ateva 2842AC is formulated into the hinge adhesive at 3038 wt% with a tall oil or hydrogenated rosin ester tackifier at 3442 wt% and a crystallizing wax at 2028 wt%. The adhesive is applied at 150168 °C through a wheel applicator or closed nozzle, followed by side gluing and cover attachment, then nipping at 0.20.6 MPa for 36 s. Cooling tunnels operating at 24 °C bring the spine below the wax crystallization transition before stacking. Compliance varies by product class: children’s books frequently require migration limits under EN 71-3; general softcover books are assessed under REACH EC No 1907/2006; and cold flex performance is confirmed by a hinged-mandrel test adapted from ISO 178:2019, with most specifications requiring no visible spine crack after 50 opening cycles at −20 °C. Terminal finished product types include perfect-bound paperbacks, catalogs, annual reports, training manuals, and magazines. A known limitation is that Ateva 2842AC-based body adhesives are not suited to UV-cured binding lines; converters needing lay-flat performance should evaluate a separate primer layer because published page-pull data for this specific single-shot configuration is limited.

    A slot-die PSA coating line handles Ateva 2842AC differently from styrenic block copolymers because it cannot be crosslinked by UV/EB and its high-temperature shear resistance is lower than SIS/SBS systems. In this application, Ateva 2842AC is compounded at 2030 wt% with a C5/C9 tackifier at 3045 wt%, naphthenic or paraffinic oil at 2030 wt%, and 05 wt% wax. The blend is metered through a gear pump at 150180 °C onto a silicone-coated release liner or directly onto a corona-treated polypropylene film at 2060 g/m² coat weight. Laminating to facestock occurs downstream in a chilled nip before slitting. Compliance for food-contact labels is covered under FDA 21 CFR 175.105 provided the adhesive layer does not directly contact food in a way exceeding the intended conditions; direct food contact is not supported. Peel adhesion and loop tack are evaluated under PSTC-101 and PSTC-16; users should request supplier-specific data because published values for this specific Ateva grade are limited for barrier facestocks. Terminal finished product types include box sealing tape, general-purpose label stock, protective masking films for appliances, and double-sided tissue tabs. The upper service temperature of such PSA is generally limited to 50 °C; exposure beyond that results in cohesive failure under shear loads.

    When Filled EVA Carries Pre-Coated Edgebanding Through High-Speed Profile Wrapping

    Pre-coated edgebanding is reactivated for profile wrapping at a surface temperature of 180200 °C, a window that requires the adhesive to melt quickly but not sag from the banding before contact. Ateva 2842AC at 3040 wt% is combined with a rosin ester tackifier at 3040 wt%, calcium carbonate filler at 1525 wt%, and wax at 510 wt% to generate the required cohesive strength after cooling. The pre-coating process uses a slot die or heated roller running at 2045 m/min, after which the edgebanding is cooled and wound. At the furniture plant, activation occurs by a hot air or infrared tunnel, followed by pressure rollers at 0.20.8 MPa on medium-density fibreboard or particleboard edges. For filled pre-coat granules, compounding in a co-rotating twin-screw extruder with an L/D of 40:1 at 130150 °C melt temperature avoids localized thermal degradation caused by high filler surface area. Compounded filled granules should be pre-dried at 60 °C for 2 h when storage relative humidity exceeds 60% to prevent foaming in the coater. Compliance does not derive from structural wood adhesive standards because edgebanding is nonstructural; the operative chemical restrictions are RoHS Directive 2011/65/EU and REACH EC No 1907/2006. Terminal finished product types include kitchen cabinet doors, office desk edges, wardrobe side panels, and retail fixture shelves. This filled system is not suitable for exterior exposure or prolonged water immersion because ester linkages in EVA and rosin ester are susceptible to hydrolysis under sustained high humidity.

    Automotive Headliner Lamination and Olefin Substrate Bonding

    Interior trim lamination requires a low-odor adhesive film or web that can bond polyethylene nonwoven, open-cell polyurethane foam, and crosslinked polyethylene foam without collapsing the substrate. Ateva 2842AC is incorporated at 2535 wt% with a fully hydrogenated tackifier and a high-melting synthetic wax to balance flow control. The adhesive film is extruded at 520 g/m², then laminating occurs in a vacuum or flatbed thermoforming press at 130150 °C for 2040 s, followed by cooling in a contoured die to retain shape. Compliance is dominated by the OEM odor and fogging protocol based on VDA 278 thermal desorption, with limits typically set per platform; the adhesive supplier is expected to report total VOC and FOG emissions rather than claim blanket compliance. REACH EC No 1907/2006 and the EU End-of-Life Vehicle Directive 2000/53/EC also require declaration of heavy metals and restricted substances. Terminal finished product types include automotive headliners, door panel inserts, seat back map pockets, and parcel shelf covers. Batch-to-batch viscosity drift is a known production issue on gravure coating lines; incoming melt index should be verified under ISO 1133-1:2022 and held within agreed limits to avoid film thickness variation. Ateva 2842AC is not combined with acid-modified adhesion promoters or amine-based processing aids in this application because ester linkage cleavage can compromise long-term laminate integrity.

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    Certification & Compliance
    More Introduction
    Ateva 2842AC is an ethylene-vinyl acetate copolymer resin specified for hot-melt adhesive compounding. The material carries a nominal vinyl acetate content of 28 wt% and a nominal melt index of 400 g/10 min when tested under ASTM D1238 at 190°C with 2.16 kg. The grade designation itself encodes the two primary specification drivers: the 28 indicates the vinyl acetate level, and the remaining digits correspond to the high melt flow class. The “AC” suffix refers to the manufacturer’s stabilization and product-revision package, not to a separate chemical family. In hot-melt formulations, Ateva 2842AC is used as the polymer backbone where low melt viscosity, rapid wetting of cellulosic and polar substrates, and compatibility with rosin ester or hydrocarbon tackifiers are required. It is not typically selected where maximum heat resistance, high cohesive strength, or very long open time is the primary requirement. Compared with lower melt index EVA grades of similar vinyl acetate content, this grade lowers melt pressure, permits finer coating control at reduced application temperature, and increases penetration into corrugated board, nonwovens, and microporous surfaces. End uses for this resin class include case and carton sealing, bookbinding, nonwoven lamination, pressure-sensitive assembly, and packaging structures where low-temperature application and fast set are needed. In spiral spray and slot-die hot-melt lines, the 400 MI flow characteristic reduces the risk of nozzle clogging at moderate temperatures and supports high line speeds; however, the low melt strength can produce adhesive bleed-through if coat weight and open time are not controlled. Formulators adjust wax content, tackifier type, and application temperature to maintain acceptable bond performance under ASTM D1876 or ASTM D903 peel methods and ASTM D4498 or ASTM D3654 shear methods.

    How Does 28% Vinyl Acetate Content Shift Hot-Melt Performance?

    At 28 wt% vinyl acetate, the ethylene crystallinity is reduced sufficiently to broaden the melting transition and lower room-temperature modulus. Differential scanning calorimetry under ISO 11357-3 typically shows a broad endotherm for similar high-VA EVA grades, with the main melting peak below 80°C; exact values for Ateva 2842AC should be taken from the manufacturer’s certificate of analysis. Polar vinyl acetate groups increase adhesion to paper, wood, coated board, aluminum, and polar polymer films. This is particularly relevant in bookbinding and packaging where fiber tear under ASTM D6436 is used as a failure criterion. The 28 wt% VA level also improves compatibility with polar tackifiers such as rosin esters and some terpene phenolic resins, permitting higher tackifier loading before phase separation becomes visible as haze or surface tack loss. The penalty is a reduction in cohesive strength and heat resistance relative to 18 wt% VA grades. In shear adhesion failure temperature testing under ASTM D4498, formulations based on 28 wt% VA typically fail at lower temperatures than formulations based on lower-VA grades at equivalent melt index. The technical value of Ateva 2842AC is therefore the ability to bond polar surfaces and formulate low-viscosity systems, not an increase in hot-bond performance. Melt-index testing under ASTM D1238 reports a single-point flow parameter, not a full viscosity curve. Capillary rheometry under ASTM D3835 or ISO 11443 is required to define the shear-thinning behavior of the formulated hot-melt. At 400 g/10 min, the neat resin is already a high-flow material; in compounds, it contributes low viscosity and may reduce the need for high levels of paraffin or Fischer–Tropsch wax to achieve target application viscosity. This is useful for spray grades and low-grammage slot-die coating; however, viscosity reduction by using high-MI EVA also reduces melt strength and can shorten the effective bonding window. On high-speed packaging lines, the lower viscosity can improve transfer and wetting at application temperatures 10–20°C below those needed for a 150 MI grade, but the formulator must verify that the bond reaches substrate fiber tear before cooling below the open time. Production experience with similar grades indicates that coat-weight variation is more sensitive to melt temperature, so heated hoses and applicator heads should be equipped with temperature controllers capable of ±5°C stability.

    Thermal Degradation Pathways and Stability Boundaries During Melt Processing

    Ethylene-vinyl acetate copolymers degrade through acetic acid elimination from vinyl acetate units when held at elevated temperature. The reaction generates acetic acid, unsaturation, and eventually crosslinked or discolored gel. For high-MI grades, the degradation rate is not necessarily higher than lower-MI grades at the same VA content, but the lower viscosity can expose the melt to more rapid convective heat transfer and may shorten perceived residence time if process controls are not adjusted. In open hot-melt tanks, degradation becomes industrially significant above approximately 180°C, and the rate accelerates sharply above 200°C. Equipment validation should include temperature mapping of reservoir, hose, and die zones because local hot spots above 200°C can create char even if the tank setpoint is lower. The stabilization package incorporated in the AC grade is designed for standard hot-melt compounding and application, but it does not permit indefinite hold times. Nitrogen blanketing of melt tanks, low-volume heated hoses, and first-in-first-out melt scheduling are used to limit oxidative degradation. Viscosity and color stability can be assessed by hot-melt aging protocols such as ASTM D4499 after 24–72 h at the intended application temperature; the pass/fail limits are set by the end product specification. A rise in melt viscosity of 15–20% from the initial value after 48 h at 180°C is often used as a plant rejection limit, though the exact limit is product-specific. Color measurements using Gardner or Hazen scales may reveal yellowing before viscosity shift. When 400 MI EVA is held at high temperature in the presence of oxygen, the outer surface of the melt can skin over, and the skin can detach into the application stream causing nozzle blockage. Melt tanks should therefore be designed for low surface-area-to-volume ratio, and recirculation loops should avoid dead zones where aged melt accumulates. Avoid compounding with strongly alkaline fillers or amine-based additives that can accelerate deacetylation. Copper and copper alloys should also be avoided in melt contact surfaces because trace copper can catalyze oxidative breakdown. Published data for Ateva 2842AC degradation kinetics under every equipment configuration is limited, so the safe approach is plant-specific qualification with viscosity, color, and adhesion checks after residence-time trials.

    When 400 MI EVA Replaces Lower Melt Index Grades

    Substitution of Ateva 2842AC for a 28 wt% VA, 25–150 g/10 min EVA is not a drop-in change. The melt viscosity decreases, and the adhesive may penetrate porous substrates before setting, resulting in visible bleed-through or a starved bond line. On corrugated packaging, fiber tear under ASTM D6436 may remain high even with lower coat weight, but edge squeeze and compression resistance can decline. In bottle labeling or bookbinding, the faster flow may improve initial wetting but reduce the open-time tolerance for aligning components. In contrast, replacing a 18 wt% VA, 400 MI EVA with Ateva 2842AC increases polarity and adhesion to coated board while shifting the heat-resistance profile downward. The formulator should compare the full thermal/mechanical profile using ASTM D4498 for shear-fail temperature, ASTM D638 or ISO 527 for tensile response of the neat or compounded material, and ASTM D792 for density if gravimetric yield is part of the cost model. Formulation development with this grade requires tracking the viscosity response across the full temperature range. In hot-melt formulations, the polymer is only one variable: resin-to-wax ratio and tackifier polarity govern open time, set speed, and peel behavior. Because 400 MI EVA already provides low melt viscosity, formulators may use lower wax levels to improve cohesion or higher wax levels to shorten set time. Rosin esters with softening points around 90–110°C are common, but exact compatibility must be confirmed by clarity and aged adhesion. Hydrocarbon tackifiers may be used for lower color and improved thermal stability; however, adhesion to polar substrates may decline more than with rosin ester. The optimum is therefore formulation-specific and is not determined by the polymer alone.
    Property/response Ateva 2842AC Lower MI EVA with similar VA Processing consequence
    Melt index ASTM D1238 400 g/10 min 25–150 g/10 min Lower application viscosity and lower pump pressure
    Melt viscosity at 180°C lower higher Thinner coating, shorter open time, higher penetration
    Shear adhesion failure temperature ASTM D4498 typically lower typically higher Reduced hot-load resistance
    Green strength develops more slowly in some formulations faster Longer compression or cooling time
    Tackifier compatibility high high Similar polar tackifier range
    Comparative difference from metallocene polyolefin elastomers and APAO is based on the same polarity–viscosity balance. mPOE grades of similar melt viscosity may provide improved thermal aging and lower odor but often require higher tackifier modification to achieve equivalent adhesion to coated board. APAO hot melts generally show longer open time and higher flexibility but lower set speed and cohesive strength; Ateva 2842AC provides a sharper set and stronger polar adhesion to cellulose. For nonwoven construction, the high flow of this EVA supports low add-on spiral spray; for automotive interior trim, its heat resistance may be insufficient unless the formulation is heavily modified. Therefore, the product is not a universal hot-melt polymer but a specific high-flow, high-polarity building block. On a 40:1 L/D co-rotating twin-screw extruder compounding a high-flow EVA, the lower viscosity reduces motor load and melt temperature but may limit dispersive mixing, especially when adding high-surface-area fillers. The formulator may need to increase screw speed or use more aggressive kneading blocks to achieve the same dispersion as with a lower-MI grade. However, excessive kneading can generate localized viscous heating above 200°C; therefore, an extruder with accurate barrel cooling and a side-stuffer for filler is preferred. In single-screw hot-melt coaters, a barrier screw with shallow metering channels may be needed to maintain output stability because the low melt viscosity can cause surging at the die if screw geometry is optimized for lower-flow grades.

    Storage, Drying, and Additive Compatibility Boundaries

    EVA is not strongly hygroscopic, but surface moisture from high-humidity storage can introduce bubbles and viscosity fluctuation in hot-melt equipment. The resin should be stored below 30°C and 50% relative humidity. If bags are opened in humid conditions, pre-drying at 60–80°C for 2–4 h in a dehumidified hopper dryer is typical before extrusion compounding; for direct hot-melt use, the manufacturer’s packaging and drying guidance should be followed. Moisture-related defects in hot-melt adhesives include bubbling in the melt tank and inconsistency in bead shape; these are usually caused by surface moisture rather than bulk absorption. A short purge at 120–140°C may remove surface moisture, but the resin should not be heated above the manufacturer’s recommended maximum. In high-humidity production environments, sealed hoppers or aluminum-laminated bags reduce moisture uptake. If the resin is compounded with hygroscopic fillers or flame retardants, drying requirements are dominated by the additive, not the EVA. Avoid contamination with polypropylene, high-density polyethylene, or styrenic block copolymer pellets because these can create gel-like domains in the melt and reduce clarity. Contact with copper, brass, or bronze fittings at melt temperature should be avoided. In formulation, low-acid-number waxes and stabilized rosin esters are generally preferred; high-acid-number resins can change the melt color and may interact with the vinyl acetate groups under extended heating.
    Standard/regulation Scope Typical test condition
    ASTM D1238 Melt flow rate 190°C, 2.16 kg
    ISO 1133-1:2022 Melt mass-flow rate 190°C, 2.16 kg
    ASTM D3418/ISO 11357-3 DSC melting and crystallization 10°C/min heating/cooling
    FDA 21 CFR 177.1350 EVA copolymers for food contact Formulation- and migration-specific
    EU 10/2011 Food-contact plastics Overall and specific migration
    REACH Registration and SVHC compliance Grade-specific substance identity
    Plant validation with 400 MI EVA should include lot-to-lot melt-index verification because coat weight and adhesive distribution are sensitive to flow variation. A shift of 10–15% in melt index may remain within a broad commercial range but can require pump-speed correction on lines without closed-loop viscosity control. In low-grammage slot-die coating for nonwovens, final coat weight may be 1–3 g/m²; at that coat weight, even small changes in melt viscosity can alter web coverage. High-shear viscous heating can raise the actual melt temperature above the reservoir setpoint; barrel and die zones must be profiled conservatively, and start-up purge times should be minimized to avoid thermal history accumulation. This final application-specific validation determines whether the grade’s high flow and polarity are acceptable for the target bond, substrate, and line speed.