| HS Code | 383132 |
| Product Designation | Kuraray K-II WN4 41 Water-Soluble PVA Fiber |
| Polymer Type | Polyvinyl alcohol (PVA) |
| Fiber Type | Water-soluble synthetic staple fiber |
| Dissolution Temperature | 40°C in water |
| Fiber Form | Staple fiber |
| Typical Cut Length | About 41 mm |
| Typical Linear Density | Approximately 4.4 dtex |
| Specific Gravity | Approximately 1.26–1.30 |
| Appearance | White to off-white solid fibers |
| Hydrophilicity | Hydrophilic; readily wettable and water-soluble at specified temperature |
| Biodegradability | Biodegradable under suitable aqueous environmental conditions |
As an accredited Kuraray K-II WN4 41-Water Soluble PVA Fiber (Dissolves at 40°C) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in 25 kg net heat-sealed polyethylene-lined bags, palletized and shrink-wrapped for safe transport and moisture protection. |
| Container Loading (20′ FCL) | 20′ FCL container loading of Kuraray K-II WN4 water-soluble PVA fiber: palletized, dry-protected, secured, avoiding moisture and heat above 40°C. |
| Shipping | Ship Kuraray K-II WN4 41 water-soluble PVA fiber in sealed, moisture-proof packaging to prevent premature dissolution. Avoid exposure to water, humidity, and temperatures above 40°C during transit. Handle gently to minimize fiber dust. Not classified as dangerous goods, but protect from rain and direct sunlight. |
| Storage | Store in a cool, dry area below 40°C to prevent premature dissolution. Keep in original, tightly sealed packaging away from moisture, humidity, and direct sunlight. Ensure no water contact during storage. Avoid excessive heat and stacking damage. Under these conditions, the PVA fiber remains stable and retains its intended solubility performance. |
| Shelf Life | Store dry and cool below 40°C. Sealed, shelf life is typically two years from manufacture under recommended conditions. |
Wet-laid filtration media lines operating at wire speeds above 120 m/min employ Kuraray K-II WN4 as a fugitive pore-forming binder rather than as a permanent structural fiber. The fiber is introduced at 2 wt% to 7 wt% of total dry furnish; below 2 wt% the pore-opening effect is masked by calendering, while at loadings above 7 wt% dissolved PVA can transfer to the surface of the first dryer can and generate a tacky deposit that increases sheet breaks. Stock pH is maintained between 6.0 and 7.5, and furnish temperature is held below 30°C because premature dissolution at or near the 40°C threshold raises dissolved-polymer content in the white water and consumes cationic retention aid. Machine chest residence is limited to 20 min or less in closed-loop systems. The sheet is formed on an inclined wire former, dewatered by vacuum boxes, and dried on a multi-cylinder section with first-can surface temperature of 95°C to 110°C; at this stage the PVA fiber enters solution and redistributes around cellulose or polyester staple intersections. After rewetting, the PVA phase leaches out and leaves a controlled void network. Sheet tensile is reported under ISO 9073-3, thickness under ISO 9073-2, and air permeability under ISO 9237; the air-permeability measurement is useful because the pore volume created by PVA removal is not reliably captured by basis weight alone. Published data for this specific K-II WN4 wet-lay configuration is limited, so mill validation should include a white-water solids mass balance and a PVA concentration check before full-scale roll production.
Temporary separation courses in garment panels are knit from K-II WN4 filament or staple yarn at counts between Nm 50/1 and Nm 80/1, with the selected count determined by machine gauge and stitch length rather than by fiber strength alone. On a single-jersey circular machine running at 0.8 m/s to 1.4 m/s, feed tension is set between 2 cN and 4 cN; tensions above 5 cN produce filament fraying at the needle latch, and the resulting PVA dust accumulates in the trick groove. The yarn absorbs moisture rapidly above 55% relative humidity, which softens the fiber surface and increases yarn-to-metal friction; this is the primary continuous-running limitation observed on production-scale machines in humid knitting and weaving sheds. Storage before knitting is therefore kept at 20°C to 28°C and below 50% RH, with cones sealed in moisture-barrier film. After garment assembly, the separation yarn is removed in a hot-water bath set at 40°C for 10 min to 15 min at a liquor ratio not below 20:1; the bath must be agitated or the PVA dissolution front stalls at the stitch interstices. Wet strength of PVA water-soluble yarn is lower than dry strength, so the bath is not used for load-bearing seams. Tensile properties are reported under ISO 2062 or ASTM D2256/D2256M-21; converting mills should use the supplier certificate of analysis because water-soluble PVA tenacity and elongation are sensitive to storage humidity. Residual PVA on the garment after washdown is checked by a cool-water rinse and hand-feel test, because finite PVA residue can re-deposit on polyester knitting oils and create a stiff edge at the former separation line.
A production-scale hydroentanglement line can process K-II WN4 staple into a 30 g/m² to 60 g/m² fabric that retains sufficient wet strength for handling contaminated linen at room temperature but disperses at 40°C in the washer. Needlepunch bonding is generally unsuitable because the high barb density and needling density required for PVA staple can fracture the water-sensitive fiber and generate short-fiber debris that does not dissolve uniformly. The preferred forming route is carding followed by low-pressure hydroentanglement using water at 10°C to 25°C; if the recycled water temperature in the injector manifold exceeds 35°C, fiber dissolution begins on the belt and creates a translucent PVA film that blocks the perforated sleeve. Fabric tensile is measured following ISO 9073-3, and bursting strength is tested to ISO 13938-1:2019; a burst strength of 80 kPa to 150 kPa at fabric weights below 50 g/m² is regarded as workable for bag conversion, but the final specification depends on bag size and seam construction. Seams are closed with water-soluble adhesive tape rather than stitching thread because thread holes remain visible after dissolution and can trap insoluble lint. Bags are used in healthcare and containment wash processes where contaminated linen is sealed at the point of use and loaded directly into a washer; the 40°C dissolution point is compatible with cold pre-wash cycles and avoids manual reopening of soiled textiles. The fabric must be stored in sealed polyethylene outer bags at 10% to 40% RH because high humidity reduces dry burst strength and can cause blocking between adjacent layers. REACH registration status for the PVA polymer and local waste-water permits for dissolved PVA should be confirmed before implementing closed-loop laundry water recovery, since dissolved PVA contributes to chemical oxygen demand and can interfere with membrane filtration if not degraded.
| Processing stage | Standard designation | Measured property |
|---|---|---|
| Wet-laid nonwoven tensile | ISO 9073-3 | breaking strength in N/25 mm |
| Yarn single-end tensile | ISO 2062 / ASTM D2256/D2256M-21 | breaking force and elongation at break |
| Laundry bag fabric burst | ISO 13938-1:2019 | bursting strength in kPa |
| Embroidery backing tensile | ISO 9073-3 | tensile strength and elongation |
| Hollow-core yarn after PVA removal | ISO 2062 | breaking force and elongation at break |
For high-stitch-count emblems and standalone lace constructions processed on multi-head embroidery lines, K-II WN4-based soluble backing is used to avoid tearing fragile stitch patterns during manual release. The backing sheet is calendered to a thickness of 0.20 mm to 0.40 mm and is hooped together with the face fabric, then embroidered at speeds of 700 to 1,000 stitches per minute using a 75/11 or 80/12 needle. The backing must resist needle puncture deflection at high stitch density; if the sheet thickness is below 0.15 mm, densely packed satin stitches cut through the backing and create loose fibers that wrap around the needle, causing thread breaks. After embroidery, the assembled piece is passed through a 25°C rinse to remove water-soluble patterning oils and non-ionic lubricants, then through a 40°C spray or immersion stage for 5 min to 10 min; the second stage dissolves the PVA backing without disturbing the embroidery structure. The wash tank is renewed at intervals based on dissolved solids; dissolved PVA concentrations above 2 wt% in the tank make the water slippery and reduce the dissolution rate of the remaining backing. Tensile strength of the backing is measured to ISO 9073-3, and bending stiffness is evaluated by the converter because needle penetration force depends on stiffness rather than tensile strength alone. Residual backing is monitored by the absence of a white film on dark embroidery after the final cold rinse; any residual PVA film becomes stiff after textile finishing and is detectable as a mirror-like patch under oblique light. Where the finished product is exported to apparel brands, the converter should verify dissolved PVA in wastewater against the receiving region’s chemical oxygen demand limits.
In core-spun yarn manufacture, K-II WN4 is used as a sacrificial core component that is removed after ring-frame spinning to produce a low-density hollow-core cotton or cotton-blend yarn. The process uses a PVA filament or staple core at 10% to 25% of final yarn mass, fed through a core-yarn attachment with controlled pretension of 5 cN to 12 cN; if pretension is too low, the PVA core migrates to the yarn surface during twisting, and if it is too high, the cotton sheath opens under the core tension and produces a slub-like fault. The sheath is spun from combed cotton or cotton/polyester staple at a twist factor of 3.8 to 4.2 (αe), because a compact sheath with adequate radial pressure is required to withstand the core removal stage and maintain the hollow channel. After the yarn is wound onto dye packages, the PVA is dissolved in a pressure dyeing vessel or package wash line at 40°C for 20 min to 40 min, with liquor flow reversed at intervals to prevent the collapsed PVA layer from channeling at the package flanges. The resulting hollow-core yarn exhibits lower bulk density and higher thermal insulation than equivalent solid yarn, but its tensile strength is reduced; yarn breaking force is evaluated under ISO 2062 and the strength loss is normally balanced by increasing the sheath cotton count by one or two yarn counts. The dissolution bath must be kept free of anionic acrylic size, because PVA can co-precipitate with acrylic size under acidic conditions and form a water-insoluble complex that cannot be rinsed from the cotton sheath. Published data for this exact K-II WN4 core-spun configuration is limited; package density, flow reversal frequency, and dissolved-PVA concentration should be validated on a pilot package machine before bulk production.
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In aqueous processing environments where temperature control below 45°C is required, Kuraray K-II WN4 is supplied as a water-soluble polyvinyl alcohol staple fiber with a nominal dissolution temperature of 40°C. The product designation K-II WN4 41 identifies the water-solubility class and the staple cut-length/fineness configuration within the manufacturer’s coding system. The controlling technical datasheet or certificate of analysis should be consulted for the exact linear density, cut length, moisture content, and package configuration. In wet-laid nonwoven furnish and papermaking, the fiber behaves as a temporary structural component: it disperses during stock preparation, contributes to sheet formation, and dissolves when the semi-dried or dried web reaches the 40°C threshold. Dissolution does not proceed by simple surface erosion alone. The fiber swells, forms a gel layer at the fiber surface, and releases polyvinyl alcohol chains into the continuous water phase. That released polymer can increase white-water viscosity, alter drainage on the forming wire, and require adjustment of retention chemistry.
On an inclined-wire fourdrinier or rotary hydroformer, production experience indicates that WN4-containing furnish is usually controlled within a surface-temperature band of 38–42°C. Below 38°C, dissolution rate slows and undissolved fiber residues may remain as sheet defects or surface deposits on downstream equipment. Above 42°C, dissolution can begin in the press section or on the first dryer cylinder, causing sheet picking, wrap events, and doctor-blade buildup. The operational window is narrower than for cellulose-only furnish because the fiber changes from a load-bearing solid to a soluble polymer within a few degrees of the nominal dissolution threshold.
Dissolution response is also sensitive to water hardness and ionic strength. Hard water containing elevated calcium or magnesium can reduce the dissolution rate by altering the hydration behavior of the polyvinyl alcohol chain. Controlled dissolution trials should therefore use deionized or softened water. A common incoming-material verification method is a weight-loss determination in deionized water at 40°C for a fixed residence time under controlled agitation. Static beaker testing is not fully representative; a stirred bath or recirculating dissolution vessel is preferred because the gel layer forms an external mass-transfer boundary that slows further hydration. Published data for complete dissolution time of this specific configuration is limited, but fiber cut length, crimp, and furnish dispersion quality all influence the observed removal rate.
Before airlay blending or carding, WN4 should be protected from relative humidity above 60%. Polyvinyl alcohol fiber is hygroscopic and can absorb sufficient moisture to cause blocking in storage hoppers, chute feeds, or bale openers. Pre-drying at 50°C may be used when condensation risk is controlled, but partial dissolution can occur if wet fiber contacts hot surfaces above the 40°C threshold.
In dry-laid nonwovens, WN4 may be blended with cellulosic or synthetic fibers at addition levels of 5% to 20% by weight and subsequently dissolved in a perforated drum washer, counterflow rinse tank, or open-width washing compartment. For papermaking furnish, addition levels are typically below 2.0% by weight because dissolved polyvinyl alcohol increases headbox viscosity and can affect formation. In porous nonwoven production, the fiber acts as a sacrificial pore former: it survives dry-laid web formation, then dissolves under controlled wet processing to leave void space. The wash water must be managed for polyvinyl alcohol concentration, temperature, and effluent load.
Table 1 lists test methods commonly associated with acceptance of polyvinyl alcohol staple fiber.
| Property | Standard or test method | Use in WN4 acceptance |
|---|---|---|
| Linear density | ISO 1973:2021 | Confirms staple fineness and supports blend-ratio calculation. |
| Breaking tenacity and elongation | ISO 5079:2020 | Verifies mechanical processing tolerance on carding or airlay equipment. |
| pH of aqueous extract | ISO 3071:2005 | Controls ionic conditions that may shift dissolution behavior. |
| Dissolution residue | Manufacturer method in deionized water at 40°C | Confirms grade identity against higher-temperature K-II types. |
The product is typically offered as short-cut staple for wet-laid and papermaking uses. Fiber lengths of 4 mm and 6 mm are common for dispersability, with 4 mm generally preferred in wet-laid stock because longer fibers can wrap around forming-wire elements or accumulate in stock-preparation equipment. The 41 suffix may denote a 4 mm cut and a nominal fineness code, but the manufacturer’s certificate of analysis remains the authoritative source for shipment-specific fiber length and linear density.
Water-soluble polyvinyl alcohol fibers are not a single product class. Higher-temperature K-II grades dissolve at 60°C to 70°C and are specified where downstream wet processing, drying, or laundering exceeds 40°C. WN4 is positioned at the lower end of the heat-solubility range. The lower dissolution threshold reduces the thermal energy required for binder removal, but it also narrows the useful processing window in heated systems. The distinction matters in cementitious composites: WN4 should not be selected as a permanent reinforcement fiber if mixing water or curing heat can exceed 40°C. Its use in cementitious materials is limited to low-temperature pore-forming or sacrificial-binder functions, and published data for that specific application is limited.
Generic polyvinyl alcohol fiber literature reports density values in the range of 1.26–1.30 g/cm³ and moisture regain near 5.0% at 65% RH. Actual WN4 values depend on degree of saponification, crystallinity, and finishing. Compared with starch-based temporary fibers, WN4 retains fiber identity at room temperature and releases a synthetic polyvinyl alcohol solution upon washing. Starch-based temporary fibers may show lower tenacity and different effluent characteristics. Compared with ethyl vinyl alcohol copolymer fibers, WN4 is designed for complete aqueous solubility rather than high ethylene-content barrier performance. Compared with polyvinyl alcohol fibers intended for permanent textile or cement reinforcement, WN4 sacrifices long-term wet resistance in exchange for predictable removal at 40°C.
In textile backings and embroidery support, WN4 can be converted into water-soluble nonwoven or woven substrates that are removed in the first rinse at 40°C. This represents a lower-temperature alternative to backings designed for dissolution at 70°C or 90°C. The selection is relevant when the face fabric contains temperature-sensitive dyes, coatings, or synthetic fibers that cannot tolerate higher washing temperatures. However, the dissolved polyvinyl alcohol remains in the aqueous phase and can redeposit during cooling. Rinse water should be maintained at or just above 40°C until dilution is adequate, and counterflow washing is preferred to reduce polyvinyl alcohol concentration in the final rinse.
When WN4 is used as a sacrificial binder in near-net-shape composite preforms, the fiber must survive dry layup but dissolve before resin injection. In such operations, cut lengths of 4 mm or 6 mm are typically specified. The shorter 4 mm staple disperses more readily in wet-laid or spray-up preforms, while 6 mm staple is used in carded or airlaid preforms where greater mechanical bridging is required. The fiber is not intended for high-loft structures requiring permanent reinforcement. It is a temporary forming aid that is removed in a temperature-controlled aqueous wash before matrix consolidation.
In water-sensitive textile scaffolds and porous membranes, WN4 can replace solvent-based binder extraction because it leaves no fibrous residue at or above 40°C. Removal equipment may include counterflow rinse tanks, perforated drum washers, or open-width washing compartments with independent water-temperature control. Counterflow operation reduces water consumption and polyvinyl alcohol concentration in the final rinse. If the final rinse contains more than 2.0% dissolved solids, cooling may create a tacky polyvinyl alcohol film on the fabric surface. Therefore, final rinse overflow and temperature control should be verified during process commissioning.
The fiber should be stored in its original moisture-barrier packaging. In warehouses where relative humidity exceeds 60%, dehumidified storage or desiccant protection is standard practice. Direct water contact before processing can fuse fiber at the bale surface and make downstream opening difficult. Supplied fiber is not a direct food-contact additive; end-use regulatory clearance for food-contact articles must be established under applicable national law, including 21 CFR where relevant. Wastewater containing dissolved polyvinyl alcohol may require COD or BOD evaluation under local discharge permits, particularly for continuous high-volume dissolution operations.