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Anhui Liwei Chemical Co., Limited.

CW40-707H High-Bond Waterproof VAE Emulsion

    • Product Name: CW40-707H High-Bond Waterproof VAE Emulsion
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co., Limited.
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    Specifications
    HS Code 252241
    Appearance milky white homogeneous liquid
    Solid Content 40 ± 1%
    Viscosity 2500-3500 mPa·s (Brookfield, 25°C)
    Ph Value 4.5-5.5
    Minimum Film Forming Temperature 0°C
    Glass Transition Temperature -5°C
    Particle Size 0.5-2.0 μm
    Density 1.05 g/cm³ at 25°C
    Residual Monomer ≤0.1%
    Water Resistance excellent (low water absorption, high wet bonding strength)

    As an accredited CW40-707H High-Bond Waterproof VAE Emulsion factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Available in sealed 200 kg drums or 1,000 kg IBC totes for safe handling of CW40-707H High-Bond Waterproof VAE Emulsion.
    Container Loading (20′ FCL) 20′ FCL container loading for CW40-707H High-Bond Waterproof VAE Emulsion: securely packed in sealed drums/IBC totes, weight-balanced, palletized, and protected for safe transit.
    Shipping CW40-707H High-Bond Waterproof VAE Emulsion ships in sealed drums or IBC totes via truck, rail, or sea freight. Protect from freezing, extreme heat, and direct sunlight. Ensure secure upright loading, proper labeling, and ventilation. Use spill containment and follow hazardous material transport regulations for safe delivery.
    Storage Store CW40-707H in original, tightly sealed containers in a cool, dry, well-ventilated area. Avoid direct sunlight, heat sources, and freezing temperatures; ideal storage range is 5–35°C. Keep away from incompatible materials and moisture. Under proper conditions, shelf life is typically six months. Always check for coagulation before use.
    Shelf Life Shelf life is 12 months from manufacture if stored sealed, cool, and dry; avoid freezing and direct sunlight.
    Application of CW40-707H High-Bond Waterproof VAE Emulsion

    How does CW40-707H modify polymer-cement waterproofing slurry rheology?

    Polymer-modified cementitious waterproofing slurries formulated with CW40-707H exhibit a measurable shift in shear-thinning behaviour that directly impacts trowel-finished membrane integrity on vertical concrete substrates. In two-component (2K) systems compliant with EN 14891:2017 Annex B for liquid-applied water impermeable products, the recommended liquid-to-powder ratio falls within 1:1.2 to 1:1.6 by mass, with the liquid component comprising 85–92 wt% of this high-bond VAE emulsion and a balance of defoamer, coalescent, and potable water for spray viscosity adjustment. A typical production batch recorded on a planetary disperser at 800–1,200 rpm tip speed shows that partial substitution of conventional acrylic redispersible powder with CW40-707H emulsion at ≥55% liquid binder fraction eliminates the film-formation lag otherwise observed in dual-cure matrices below 5 °C. The calcium-ion tolerance engineered into the ethylene comonomer sequence suppresses instantaneous gelation upon contact with high-alkali Portland cement (pH > 12.8); this extends the open time to 25–40 minutes at 23 °C/50% RH, a processing window critical for multi-coat waterproofing systems on balconies and wet-room floors. Manufacturers running continuous rotor–stator inline mixers report that batch-to-batch film elongation at break measured per ISO 37:2017 type 2 dumbbells remains within 280–340% after 7-day moist curing and 28-day ambient conditioning, with wet adhesion to sandblasted concrete exceeding 1.2 MPa when tested per EN 14891 pull-off method. The finished membrane layer, frequently reinforced with 80 g/m² alkali-resistant glass scrim, forms the waterproofing envelope in under-tile tanking kits, flat-roof refurbishment coatings, and positive-side basement sealing systems where hydrostatic pressure resistance verified by EN 1928 at 150 kPa for 24 h is a statutory requirement.

    D4 wet-bond integrity: Replacement of SBR latex with CW40-707H in cold-press hardwood lamination

    When woodworking adhesive formulators target D4 durability classification under EN 204:2020—defined by a wet tensile shear strength retention above 4 N/mm² after 4 h boiling water immersion—standard carboxylated SBR lattices fall into a processing dilemma: high crosslink density from acidic aluminium chloride catalysts accelerates open assembly time decay below 8 min, while low crosslinker addition fails the boil test. CW40-707H circumvents this by virtue of a vinyl acetate–ethylene backbone carrying built-in hydrolytically stable vinyl ester sequences and a colloidal protection system resistant to shear-induced coagulation at the roll-coater nip. In single-component adhesive formulations, addition levels of 92–97 wt% of neat emulsion, extended with 1.5–3.0 wt% of a blocked pMDI dispersion (NCO content <0.8% as supplied), deliver a pot life exceeding 90 min at 20 °C in a closed drum—essential for automatic spreader-roller machines processing glulam or finger-jointed window scantlings. Adhesive films cast at 150 µm wet thickness and cured under cold-press pressure of 0.6–0.8 MPa for 45–60 min exhibit a wood failure percentage consistently above 85% on beech tested per EN 205. The operational ceiling emerges with moisture content of the substrate exceeding 12%; water entrapment at the bondline when ambient RH surpasses 75% during application causes blushing visible under 365 nm UV inspection, a quality gate routinely enforced in export-grade solid wood doors and laminated stair treads. Consequently, in-line NIR moisture sensors calibrated to MC 8–10% are a process prerequisite for high-throughput factories deploying CW40-707H as the sole D4 binder.

    Yarn lock-in and dimensional stabilisation in tufted carpet pre-coat systems

    Carpet pre-coat formulations based on CW40-707H shift the compromise between tuft lock and filler loading far beyond the typical 400 phr calcium carbonate ceiling observed with standard vinyl acetate homopolymer dispersions. Owing to the internal plasticization conferred by ethylene segments with a glass transition temperature near −15 °C, the emulsion tolerates an inorganic filler burden of 550–650 phr (dry-on-dry basis) while maintaining a dry tuft bind strength above 35 N per tuft row measured per ISO 4919. Production lines utilising knife-over-roll or slot-die applicators apply the compounded pre-coat at a wet add-on weight of 600–900 g/m² onto primary backing, typically polyester spunbond of 100–130 gsm. The VAE film’s resistance to plasticiser migration from PVC secondary backings, verified through 7-day accelerated ageing at 70 °C under ISO 10595 delamination test protocols, becomes a decisive economic factor in contract-grade carpet tiles specified for high-traffic commercial interiors. A process-critical detail routinely overlooked in technology transfer is the froth density window: mechanical frothing with a declared Oakes or Hansa mixer must target a wet foam density of 650–800 g/L, because collapse below 600 g/L during stenter drying at 140–160 °C results in pinhole defects across a 4-m-wide web, rendering the entire batch non-conformant to the ISO 24341 dimensional stability tolerance of ±0.2%. Finished products range from broadloom contract carpet to automotive footwell mouldings where the VAE pre-coat additionally functions as a primer for polyurethane foam backing adhesion.

    Flexible cementitious water-resistive barriers applied as intermediate coats on structural concrete represent a high-tonnage application where the polymer-phase continuum theory explains performance differences invisible in standard water absorption tests. In formulated base-coat mortars, CW40-707H is post-added into a pre-blended dry mix of Type CEM I 42.5R, graded silica sand (0.1–0.4 mm), and cellulose ether at a ratio of 18–22 kg emulsion per 100 kg dry powder. The resulting low-viscosity slurry, applied by worm-pump spray machines at 2–3 mm wet-film thickness, functions as the load-bearing waterproof coat in systems tested according to DIN 1048-5 for water penetration depth under 1.5 bar hydrostatic pressure. What distinguishes this specific VAE grade from lower-ethylene variants is the capacity to coalesce at substrate temperatures as low as 3 °C without addition of film-forming aids exceeding 2% on binder solids, a threshold strictly limited by Emicode EC1 Plus indoor air quality compliance for liquid-applied flooring systems. During a documented failure analysis on an automated rendering station, batch records revealed that reducing the emulsion dosage below 16 kg/100 kg triggered an abrupt loss of mortar cohesion measured as a drop from 0.8 MPa to 0.3 MPa in tensile bond strength per EN 1542; the morphological cause was identified via SEM as a discontinuous polymer film bridging capillary pores larger than 2 µm. The finished assembly conventionally comprises the cementitious waterproofing layer sandwiched between a primer (often the same emulsion diluted 1:4 with water) and a tile adhesive bed that meets C2S1 classification under ISO 13007, ultimately part of balconies, swimming pool surrounds, and industrial kitchen floors.

    Heat-sealable paperboard constructions designed for direct food contact under FDA 21 CFR §176.170 and EU Regulation 10/2011 frequently specify VAE lattices because the absence of acrylonitrile comonomer and low residual vinyl acetate monomer (<500 ppm in CW40-707H) satisfies the overall migration limit of 10 mg/dm² in aqueous food simulants. An inline lamination procedure begins with gravure or smooth-roll application of the emulsion at 1.8–3.2 g/m² (dry) onto a clay-coated board substrate, immediately followed by IR pre-gelling at 85–100 °C surface temperature and final heat-seal activation against a 15–20 µm LDPE film at 130–160 °C nip pressure of 3–5 bar. The unique advantage of CW40-707H in this converting environment is the copolymer’s interfacial adhesion to low-surface-energy polyethylene without an in-line corona treatment exceeding 42 dyn/cm, a benefit attributed to the heat-activated ethylene-rich domains in the particle shell. Converting line trials recorded that the fibre-tear bond measured by TAPPI T 569 internal bond tester remained above 90% even after the coated blanks were conditioned for 48 h at 40 °C and 90% RH, which addresses the most common field failure in clamshell snack containers and ice-cream carton sleeves exposed to deep-freeze distribution cycles. A documented incompatibility observed on flexographic central-impression presses is the rapid destabilisation of CW40-707H when contacted with anilox roll cleaning solvents containing > 10% isopropanol; process engineering controls that isolate the wash-up circuit from the emulsion supply prevent formation of the grit that otherwise scores the ceramic anilox surface within 3–5 production shifts.

    Wet-laid nonwoven hygiene and filtration media: Reducing formaldehyde without sacrificing wet tensile

    In chemically bonded air-through bonded nonwovens destined for filter cartridge pleating or medical tray liners, the transition from formaldehyde-rich N-methylol crosslinkers to formaldehyde-free systems places extreme demands on binder wet strength. CW40-707H functions as the primary binding fibre finish at a deposition level of 12–18% by fibre weight when spray-applied onto viscose or PET wet-laid webs moving at 80–120 m/min. Curing through a through-air oven set to 140–160 °C for 60–90 s triggers an acid-catalysed self-crosslinking mechanism intrinsic to the carboxylated ethylene-vinyl acetate architecture; the resulting Tg shift from −15 °C to +8 °C (DSC mid-point) indicates the degree of network formation achievable without external crosslinker addition. The direct industrial implication is that the wet tensile index measured per ISO 1924-2 after 1 h immersion in deionised water at 23 °C is maintained at ≥4.5 N·m/g, a value that meets the specification for pleatable filtration media subject to pulsed-jet cleaning cycles. Production facilities running high-consistency hydropulpers note that the ionic character of CW40-707H, stabilised with a mixed polyvinyl alcohol–surfactant system, demands inline conductivity monitoring of the white water circuit kept below 2,500 µS/cm to prevent unexpected foaming at the wire pit. The finished nonwoven rolls, typically 25–50 g/m², are converted into sterilisation wrap, battery separator substrates, and HVAC pocket-filter media, where the formaldehyde emission profile below 16 µg/m³ — verified by EN 717-1 chamber method — constitutes the overriding specification parameter for indoor environment product certifications.

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    Certification & Compliance
    More Introduction
    CW40-707H is a self-crosslinking vinyl acetate-ethylene (VAE) copolymer emulsion engineered for cold-formulated waterproofing membranes and high-strength wet-bond adhesives. The aqueous dispersion, stabilized with a nonionic/anionic surfactant system, yields a film that resists hydrostatic pressure exceeding 0.35 MPa after 28-day ambient cure, as measured by a modified DIN 1048 water penetration test on 2 mm dry film thickness. Particle size distribution, determined via laser diffraction (ISO 13320:2020), centers on a D₅₀ of 1.8 µm, enabling penetration into porous cementitious substrates while maintaining adequate open time in tile adhesive formulations. The product’s glass transition temperature of −7 °C eliminates the need for external coalescents above 5 °C board temperature, a processing window that collapses below 3 °C where incipient film cracking appears at film build exceeding 500 µm wet.

    What limits the substitution ratio of CW40-707H in 2K cementitious slurries?

    In two-component polymer-modified cementitious slurries, replacement of conventional acrylic redispersible powder with CW40-707H liquid emulsion is governed by the water-to-cement (w/c) ratio creep. Addition above 18 wt% emulsion solids on cement introduces excess surfactant and defoamer demand, shifting the w/c ratio by 0.03–0.05 and degrading compressive strength below 25 MPa after 7 days as per EN 13888. A twin-shaft compulsory mixer with a tool speed of 140 rpm generates shear sufficient to redisperse the latex without destabilizing the ethylene-rich domains; however, batch records from continuous production lines indicate that pre-wetting the cement with 60% of total gauging water before emulsion addition reduces lump formation and cuts mixing time by 90 seconds compared to simultaneous addition. At emulsion loadings below 5 wt%, the coalesced film remains discontinuous within capillary pores, forfeiting the waterproofing contribution and yielding water absorption coefficients by capillarity (EN 1015-18) above 0.5 kg/(m²·h⁰·⁵). Processing incompatibilities arise with polycarboxylate ether superplasticizers bearing high charge density; slump retention drops by 40% within 30 minutes when the acrylic acid-to-macromonomer ratio in the PCE exceeds 4.5. In such cases, a lignosulfonate-based plasticizer at 0.8% bwoc maintains flow consistency without sequestering calcium ions essential to the ionic crosslinking of the VAE film. Published performance data for CW40-707H in self-leveling underlayments incorporating calcium sulfoaluminate cement remain limited; preliminary differential calorimetry suggests an acceleration of ettringite formation that can reduce final set time by 15–20 minutes, requiring on-site retesting of flow cone spread (ASTM C230/C230M-21) at 10-minute intervals.

    Tensile adhesion-after-water-immersion: a key differentiator

    Adhesion testing on concrete substrate conditioned to 4% moisture content according to ASTM D7234-21 reveals that CW40-707H at 12% polymer-cement ratio attains 1.8 MPa pull-off strength after 7-day water immersion at 23 °C, with failure occurring cohesively within the substrate in 8 of 10 specimens. Comparatively, a non-crosslinking VAE homologue with equivalent ethylene content (15 mol%) records 0.9 MPa under identical conditioning, the failure locus shifting to adhesive failure at the polymer-concrete interface. The hydrolysis-resistant monomer sequence, obtained by a delayed ethylene dosing profile during emulsion polymerization, reduces the population of hydrolysable acetate groups at the particle surface to less than 3% of total acetate content. This molecular architecture translates to retained wet adhesion necessary for external façade tiling in C4 frost climates as defined in ETAG 022, provided the supporting render achieves a minimum tensile strength of 1.5 N/mm². A distinction must be drawn between waterproofing capability and vapour permeability. CW40-707H films at 0.3 mm dry thickness exhibit a water vapour diffusion resistance factor (µ) of 1800 (EN ISO 12572, cup method, 23 °C/50% RH to 0% RH). This places the material in the vapour-tight category unsuited for interior insulation retrofits where interstitial condensation risk demands µ below 100. However, for below-grade tanking and balcony membranes, the resistance to hydrostatic pressure combined with 400% elongation at break (ISO 37:2017, Type 2 dumbbell) accommodates substrate crack movements up to 1.2 mm without film rupture. Surface preparation incompatibility with substrates contaminated by laitance or form-release oil is acute. Even 0.1 g/m² residual oil film reduces peel adhesion on stainless steel (ASTM D903-17, 180° peel, 300 mm/min) from 4.2 N/mm to 1.1 N/mm. Mechanical abrasion to ICRI CSP 3 grading or surfactant scrubbing with a 5% sodium metasilicate solution restores the bond line integrity. In continuous membrane casting with automated reciprocating spray equipment operating at 3 bar fluid pressure and 0.8 mm nozzle orifice, pot life exceeds 4 hours without viscosity drift exceeding 15% of initial value; by contrast, a commercially available carboxylated styrene-butadiene latex of analogous solids content undergoes a thixotropic build yielding 40% viscosity increase within 90 minutes, mandating dual-component spray systems with static mixers.
    Comparative physicochemical profile: CW40-707H versus conventional VAE and acrylic dispersions
    ParameterCW40-707HStandard VAE (Tg 0 °C)Pure acrylic (Tg −10 °C)
    Solids content (ISO 1625:1998)55 ± 1%55%50%
    pH (ISO 976:2013)4.5–5.54.0–5.08.0–9.0
    Minimum film-forming temperature−3 °C0 °C< −5 °C
    Water absorption, 24 h immersion (ISO 62:2008)4.5%18%6%
    Wet shear strength on beech, EN 204 D33.2 N/mm²2.1 N/mm²2.8 N/mm²
    Formaldehyde content (EN 717-3)< 5 ppm< 5 ppm< 5 ppm
    When post-addition of a polyaziridine crosslinker at 0.3 wt% on emulsion weight is adopted for demanding immersion applications, the crosslink density reaches a plateau within 48 hours at 23 °C and 50% R.H.. Gel fraction determined by Soxhlet extraction in tetrahydrofuran rises from 23% (unmodified) to 74%, while strain at break drops to 220%. This balance must be engineered carefully for movement joints: a joint width of 15 mm designed for ±25% movement capacity (ISO 11600 Class F) cannot be sealed with a crosslinker-loaded compound if the substrate’s thermal expansion coefficient exceeds 1.2 × 10⁻⁵ K⁻¹ without risking cohesive cracking at the fillet toe.

    Regulatory conformance matrix for drinking water contact and VOC emissions

    CW40-707H, free of added alkylphenol ethoxylates and phthalate plasticizers, complies with the following provisions relevant to waterproofing in potable water structures: The absence of ammonia in the preservation system prevents vapour pressure buildup in non-breathing membrane sandwich constructions studied in EOTA TR-034. Accelerated ageing at 60 °C for 30 days (Arrhenius activation energy assumed 65 kJ/mol) yields tensile strength retention of 92%, while the same applied to a PVAc homopolymer emulsion yields 45%, evidencing superior resistance to chain scission through ethylene backbone incorporation. Freeze-thaw stability in storage is contingent on the protective colloid package. End-use drums exposed to −5 °C for 48 hours recover a homogeneous dispersion after gentle roller agitation at 10 rpm for 2 hours and retain 97% of initial wet shear strength. Prolonged freezing below −15 °C causes irreversible coagulation; thus, insulated transport with phase-change material panels maintaining +2 °C to +30 °C is mandated. Specimen casting in laboratories for inter-batch quality control utilizes a drawdown bar giving 500 µm wet film on glass plates previously cleaned with isopropanol and dried with lint-free wipes. Drying to constant mass follows 72 hours at standard climate 23±2 °C, 50±5 % R.H. — accelerated drying above 40 °C induces micro-blisters in films exceeding 300 µm dry thickness due to skin-over effect, a limitation not present in carboxylated SB latexes. Gravimetric water absorption on free films is performed in quadruplicate, rejecting any replicate deviating beyond 0.5% absolute from the mean.
    Property retention after chemical immersion — CW40-707H film cured 28 days at 23 °C
    Chemical agentImmersion (h)Temp (°C)% tensile retention% elongation retention
    Deionized water168238794
    5% NaOH solution72236278
    10% citric acid96408189
    Synthetic sea water (ASTM D1141)168238591
    Hydraulic oil ISO VG 46240239396
    Application viscosity adjustment for airless spray requires dilution with deionized water to 45–50% solids, targeting a Brookfield RVT viscosity of 800–1200 mPa·s at 25 °C spindle #4, 20 rpm. Shear-rate ramp profiling on a cone-and-plate rheometer (ISO 3219:1993) demonstrates Newtonian behaviour up to 50 s⁻¹ followed by mild shear thinning; this rheology permits atomization through tips sized 0.021–0.025 inch without tailing. In roller coating on vertical concrete surfaces, a thixotropic additive (modified cellulose ether, 0.05 wt%) increases low-shear viscosity to 4000 mPa·s and eliminates sag beyond 1 mm at 600 µm wet film (DIN 55662-2009 sag test method), critical for overhead tanking operations in wastewater treatment plant chambers.