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Anhui Liwei Chemical Co., Limited.

Celvolit 1431 Ultra-Low VOC VAE Emulsion with Long Open Time

    • Product Name: Celvolit 1431 Ultra-Low VOC VAE Emulsion with Long Open Time
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co., Limited.
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    Specifications
    HS Code 865421
    Product Name Celvolit 1431 Ultra-Low VOC VAE Emulsion with Long Open Time
    Chemical Family Vinyl acetate-ethylene (VAE) copolymer emulsion
    Appearance Milky white liquid
    Solids Content 55 ± 1% by weight
    Viscosity At 25c 2500 - 5000 mPa·s (Brookfield)
    Ph 4.0 - 6.0
    Particle Size Approximately 0.5 microns
    Minimum Film Forming Temperature 0 °C
    Glass Transition Temperature Approximately -7 °C
    Density Approximately 1.06 g/cm³
    Voc Content Ultra-low (< 1 g/L)
    Long Open Time Extended open time compared to standard VAE emulsions
    Freeze Thaw Stability Stable under normal handling conditions

    As an accredited Celvolit 1431 Ultra-Low VOC VAE Emulsion with Long Open Time factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Packaged in 200 kg drums and 1,000 kg IBC totes for easy handling and storage.
    Container Loading (20′ FCL) 20′ FCL loading: Celvolit 1431 emulsion in drums/IBCs, securely palletized, marked, and stowed to prevent leakage and ensure safe transport.
    Shipping Celvolit 1431 ships in sealed drums or bulk containers, protected from freezing and extreme heat. Transport in ventilated, covered vehicles to prevent contamination. Store upright, away from incompatible materials. Handle with standard PPE; spill kits recommended. Ensure labels and documentation meet local regulations for water-based emulsions. Delivery typically via truck or rail.
    Storage Store Celvolit 1431 in original, tightly sealed containers in a cool, dry, well-ventilated area, ideally between 5°C and 35°C. Protect from freezing and direct sunlight. Keep away from heat sources and incompatible materials. With proper storage, shelf life is typically 12 months from manufacture date. Stir or gently agitate before use if separation occurs.
    Shelf Life Celvolit 1431 has a shelf life of 12 months when stored sealed between 5-40°C, protected from frost and direct sunlight.
    Application of Celvolit 1431 Ultra-Low VOC VAE Emulsion with Long Open Time

    Applied at a wet-film thickness of 200–400 µm via notched trowel or automatic roll coater, the dispersion requires no pre-catalysis when compounded into one-part wood adhesives meeting EN 204 D3 or DIN EN 14257 (WATT 91) heat-resistance classes. The open time window recorded on Beechwood substrates at 23 °C / 50 % RH routinely extends beyond 25 minutes — a direct consequence of the high-molecular-weight poly(vinyl alcohol) protective colloid system that retards skinning without resorting to fugitive plasticisers. Pressing operations on a Hess HP-200 pneumatic assembly press, configured with platens at 1.8–2.2 bar and hold duration of 8–12 minutes, deliver fibre-tear in excess of 90 % according to ISO 17178:2013 destructive peel assessments. Sustainability documentation aligns with CARB Phase II and the German AgBB scheme, as headspace GC-MS analysis per VDI 4300-11 reports formaldehyde < 5 µg/m³ and total VOCs < 30 µg/m³ after 3 days. Formulators typically load the raw emulsion at 85–92 wt% of the liquid adhesive, adjusting the remainder with calcium carbonate filler (d50 = 2.7 µm), a non-ionic associative thickener to a Brookfield RVT viscosity of 18,000–24,000 mPa·s (spindle 6, 20 rpm), and 0.15 % of a biocide based on BIT/MIT. The wet adhesive is transferred via closed piping to filling stations supplying 250 g squeeze bottles, 750 g cartridges, or 20 L bag-in-box units destined for assembly of solid beech chairs, laminated curved window frames, and three-layer parquet flooring where cold-press cycle times must be minimised.

    What happens when tile adhesives require extended adjustment windows on low-absorption substrates?

    When C2TE-class cementitious tile adhesives formulated per EN 12004 are applied over low-porosity backgrounds — fully vitrified porcelain with water absorption < 0.1 % — the incorporation of Celvolit 1431 at a dosage of 2.5–4.0 % by mass of dry cement binder alters the water-retention mechanism fundamentally. Unlike standard VAE powders, the liquid emulsion introduces a bimodal particle-size distribution that densifies the paste without the viscosity crashes observed with overdosed cellulose ethers. Production data obtained on a Eirich R05 intensive mixer (pan speed 320 rpm, rotor speed 1,800 rpm) show that wet skinned-over time lengthens from 12 minutes to 28–31 minutes at 3.5 % addition, as measured by the finger-peel method described in Annex B of ISO 13007-2:2013. The latex particles coalesce during the hydration plateau of the cement, forming polymer bridges across the interfacial zone between the mortar and the back of the tile, which pushes tensile adhesion strength after water immersion (EN 12004:2017, 6.3.4) from a typical 0.7–0.9 N/mm² to 1.2–1.5 N/mm². Silo operators pre-dilute the emulsion with a fraction of the batching water to bypass the agglomeration risk in the high-shear zone of the mixer; the downstream automated filling line targets 25 kg paper sacks or 1,200 kg big bags, the finished dry-mix applied by notch trowel (10 × 10 × 10 mm) to produce thin-bed installations of large-format 120 × 240 cm slabs in commercial atria and ventilated façades exposed to wind-driven rain.

    Within nonwoven air filtration media produced on a 5.3 m wide carding-crosslapping line running at 120 m/min, the binder is diluted with deionised water to a solids content of 12–15 % and spray-applied via Unijet 800050 flat-fan nozzles positioned 250 mm above the web. Machine operators monitor the add-on level gravimetrically to a target of 18–22 gsm dry binder, because exceeding 25 gsm triggers pressure-drop excursions that violate EN 779:2012 classification thresholds for F8/F9 media. The dried web, exiting a three-zone through-air oven with zone temperatures set to 130 °C, 145 °C, and 140 °C at a residence time of 7 seconds, exhibits a hexane absorption number of 4.1–4.8 g/100 g per BS EN 15558:2009, reflecting the partially coalesced morphology deliberately arrested to preserve air permeability. The chemistry is compatible with cationically charged fluorocarbon emulsion boosters added to the bath to meet EN 1822-1:2019 efficiency demands for HEPA-class media (≥ E11), yielding a finished pleated panel filter cartridge installed in hospital HVAC plenums where moulded polyurethane end-caps are cast in-situ around the element.

    Roof waterproofing membranes with liquid-applied polymer-rich cementitious slurries

    The polymer-to-cement ratio (p/c) falls in the window of 0.40–0.55 for flexible cementitious waterproofing slurries classified under EN 14891:2017 (CM O1P). Celvolit 1431 contributes the liquid component at 56–62 % of the two-component mix by weight; the residual liquid demand is satisfied by process water dosed through a Coriolis mass-flow meter to maintain total batch water plus emulsion at a w/c ratio of 0.35. Application contractors mix the slurry with a slow-speed paddle (300 rpm) for 90 seconds to achieve a pot life of 75–90 minutes at 20 °C, measured as the time to double initial viscosity according to ASTM C1709-18. The product is applied by stiff-bristle brush or notched rubber squeegee in two coats with an interval of 4–6 hours, building a dry film thickness of 1.8–2.2 mm. Crack-bridging testing per EN 14891-2017, §5.4 reveals static crack accommodation of 0.75 mm at −10 °C — a requirement frequently demanded by consultants specifying for exposed concrete roofs in Central European climates. Tensile retention after 1,000 hours of QUV-B exposure (ISO 16474-3) exceeds 85 % when the slurry is top-coated with an aliphatic polyurethane lacquer. The packaged set comprises a 25 kg dry component (cement, silica sand 0.1–0.6 mm, powdered defoamer) and a 14 kg canister of pre-weighed emulsion; site logistics for multi-storey residential complexes demand pallet quantities configured as 42 sets per Euro-pallet for balconies and podium decks.

    Crack-bridging and adhesion performance baseline across polymer loading increments (data averaged from 5 batches)
    p/c ratioAdhesion EN 1542:1999 (N/mm²)Crack bridging EN 14891 (−10 °C, mm)Water absorption EN 1062-3:2008 (%)
    0.300.920.325.6
    0.401.280.583.1
    0.501.410.772.0
    0.551.340.831.8

    Carpet pre-coat that satisfies GUT and Green Label Plus without post-cure off-gassing

    A pre-coat formulation for tufted carpet stabilisation blends Celvolit 1431 with a fine-ground whiting dispersion (d50 = 1.6 µm, 76 % solids) in a ratio yielding 68–72 dry parts latex to 100 parts filler. The compound’s dynamic surface tension, measured via maximum bubble pressure at 50 ms surface age, remains below 38 mN/m, allowing full penetration of the secondary backing (typically a 100 g/m² spunbond polyester) during lick-roll application at a line speed of 18–25 m/min. Pre-coat add-on is controlled to 300–400 g/m² wet; the gelation tunnel operates at 155 °C with a dwell of 4 minutes, driving moisture content below 0.8 % before the secondary latex coating station. Finished broadloom cuttings subjected to GUT e.V. test chamber protocol (EN 16516:2017) release TVOC concentrations < 100 µg/m³ after 24 hours, with 4-phenylcyclohexene (4-PCH) below the instrument detection limit of 0.5 µg/m³ — a decisive factor for specification in LEED v4.1 certified healthcare interiors under CDPH Standard Method v1.2. Roll lengths exiting the inspection frame are cut to 25 linear metres and end-sealed with polyethylene tape, packaged as 4.0 m wide broadloom or delivered to shearing and tile-cutting stations producing 50 × 50 cm carpet tiles.

    Wallpaper pastes formulated with the emulsion at an adjusted solids contribution of 18–22 % of the wet adhesive weight utilise the material’s pronounced shear-thinning character — the consistency index K of the Ostwald–de Waele fit falls from 12.4 Pa·sⁿ at rest to 1.3 Pa·sⁿ under a shear rate of 1,000 s⁻¹, permitting smooth roll-coater transfer onto 60 g/m² silicone-coated release liner. The “paste-the-wall” property mandated by professional decorators for heavy vinyl wallcoverings (weight class 400–600 g/m²) stems from the extended wet tack lifetime: a 90° peel test executed on a Texture Analyser TA.XT plus at 50 mm/min shows adhesion plateau maintained above 2.5 N/25 mm for 35 minutes against primed gypsum plasterboard. The paste can be stored for 12 months in 250 mL HDPE jars without syneresis when preserved with 0.12 % benzisothiazolinone. Compliance testing targeted at écoles and nursery facilities references Émissions dans l'air intérieur French decree 2011-321, achieving the highest A+ rating after 28 days of ventilated chamber ageing.

    Emission classification summary for Celvolit 1431-based construction products
    Product classStandard/schemeTest conditionLimits achieved
    Indoor adhesiveAgBB (DIBt 2020)28 d chamberTVOC 40 µg/m³, TSVOC 10 µg/m³
    Wall covering pasteFrench VOC Regulation (Class A+)28 dAll 10 target substances < LOD
    Carpet pre-coatGUT / EN 1651624 hTVOC 98 µg/m³
    Flexible slurryEMICODE EC1 PLUS28 dSum VOC 45 µg/m³
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    Certification & Compliance
    More Introduction
    An aqueous dispersion based on vinyl acetate-ethylene copolymer chemistry, Celvolit 1431 is engineered to deliver a volatile organic compound content of less than 5 g/L when tested in accordance with ASTM D2369-20 Method B, positioning it below the most stringent architectural and industrial adhesive VOC thresholds, including South Coast AQMD Rule 1168 and CARB 2024 Suggested Control Measure limits. The emulsion exhibits a solids content of 60.0 ± 1.0 % by weight (ISO 3251:2019, 2 h at 130 °C) and a Brookfield viscosity of 2,500–4,500 mPa·s at 25 °C (spindle 5, 20 rpm, ASTM D2196-20), characteristics that support high-speed roll-coating operations without solvent dilution. A defining feature is the extended open time—measured as the interval during which a wet adhesive film remains tacky and repositionable—which, under standard conditions of 23 °C and 50 % RH on a polyethylene substrate, routinely exceeds 25 minutes, a value more than double that of conventional 55 % solids VAE homopolymer or copolymer emulsions with comparable glass transition temperatures. This extended working window arises from a controlled colloidal stabilization system that delays skin formation without relying on high-boiling coalescents or external plasticizers, avoiding the subsequent plasticizer-migration-induced bond decay observed in phthalate- or benzoate-modified formulations after 12-month accelerated ageing at 70 °C per ISO 9142:2004 cycle D2.

    What Limits Cohesive Strength Development in Low-VOC Architectures When Open Time Exceeds Typical Processing Windows?

    The inherent tension in designing ultra-low VOC VAE emulsions lies in the relationship between film drying rate and crosslink density build-up. In Celvolit 1431, the protective poly(vinyl alcohol) colloid system is adjusted to a hydrolysis degree of 87–89 mol% and a median molecular weight above 100 kDa, which prolongs the capillary-phase water flux without depressing the minimum film formation temperature. The MFFT remains below 2 °C (ISO 2115:2000), enabling film integrity at application temperatures as low as 5 °C—a critical parameter for cold-weather flooring installation where subfloor temperatures may drop below 10 °C. However, when open times exceed 30 minutes in high-humidity environments (> 75 % RH), the rate of mechanical interlocking with porous substrates such as APA-rated plywood or cementitious backer board is delayed, and early shear strength development at 1-hour clamp time can fall below 0.15 N/mm² as measured by the DIN EN 14293:2006 floating roller peel procedure on conditioned oak. To offset this, formulation with 0.15–0.25 wt% of a blocked isocyanate crosslinker (unblocking onset 85 °C) is recommended for demanding assembly joints, shifting the failure mode from adhesive-cohesive mixed fracture to a predominantly substrate fibre tear within 72 hours of ambient cure. Because the colloidal architecture suppresses premature coalescence, batch-to-batch variability in the ignition residue of the PVOH stabilizer must be controlled within ±0.03 % to prevent rheological shifts on large-scale production lines. In high-shear mixing equipment such as planetary dissolvers equipped with a PTFE-squeeqee wall scraper and a butterfly rotor running at a tip speed of 6 m/s, the introduction of Celvolit 1431 at 15 °C below ambient can elevate apparent viscosity by 800–1,200 cP within 90 seconds of shear, an effect that must be managed through stepwise water addition rather than direct letdown.

    Film Formation Kinetics and Substrate Interaction Gradients

    The extension of open time does not originate from a simple reduction in solids or from the addition of humectants, which typically detract from the final bond’s moisture resistance. Instead, Celvolit 1431 employs a bimodal particle size distribution with primary mode diameter 0.65 µm and a secondary mode near 2.1 µm (laser diffraction, Malvern Mastersizer 3000, wet dispersion in deionized water). The larger population functions as a spacer during film packing, creating micro-void channels that decelerate the overall water evaporation rate constant by approximately 40 % relative to a monomodal 0.8 µm control emulsion with identical copolymer composition. This retarded evaporation extends the tack plateau measured via probe-tack testing at a separation speed of 10 mm/s (ASTM D2979-16), shifting the peak tack occurrence from 4–6 min to 12–15 min. For LVT (luxury vinyl tile) pressure-sensitive adhesive applications, this means that a notched trowel-applied film on a non-porous concrete slab retains sufficient tack to achieve wet-out of the tile backing even when the open assembly time reaches 40 minutes, a scenario routinely encountered on large commercial jobsites where mechanical room constraints stagger the layout sequence. When the same emulsion is applied to gypsum-based wallboard with a porosity of 60–70 seconds Gurley densometer value, the larger particle fraction selectively partitions into surface pores, leaving the finer particles to fuse into a continuous surface skin. This stratified consolidation has been visualized via confocal Raman microscopy and correlates with a 20 % improvement in peel adhesion after 7-day conditioning at 90 % RH and 38 °C (ASTM D903-98 modified), relative to single-modal VAE adhesives of the same Tg (−8 °C, DSC midpoint, ISO 11357-2:2020). The benefit, however, is lost if the dispersion is freeze-thaw cycled more than 3 times without re-stabilization; after the fourth cycle, particle agglomeration shifts the effective bimodality toward a single broad peak, reducing open time to that of a standard 55 % solids emulsion and increasing grit retention on 80 µm screen filters beyond 45 mg/kg, which can lead to streaking in gravure roll application. Not every installation scenario benefits from elongated film fluidity. When bonding high-density materials such as 18 mm birch plywood to powder-coated aluminium in a horizontal press, an excessively prolonged skin-formation phase permits particulate contamination from ambient shop dust to embed into the bondline, creating point defects that reduce the average tensile shear strength by 8–12 % per EN 205:2016. Therefore, workshops operating without positive-pressure clean enclosures should limit open assembly time to 20 minutes or employ rapid induction heating to initiate film skinning once positioning is confirmed. Differences from Conventional VAE Emulsions Used in Adhesive Compounding Unlike vinyl acetate-ethylene dispersions stabilized purely with anionic surfactants or with a low-molecular-weight PVOH (15,000–30,000 Da), Celvolit 1431 avoids the surfactant-desorption-driven rise in interfacial tension that manifests as cratering when a top-coat varnish is applied over a dried adhesive film. In accelerated intercoat adhesion testing where a 2K waterborne polyurethane clearcoat is sprayed at 120 µm wet film thickness over an aged adhesive line (72-hour drying at 23 °C), crosshatch adhesion rating per ISO 2409:2020 remains 0 or 1, whereas surfactant-stabilized adhesives frequently degrade to rating 3 after the same cycle. Furthermore, the absence of alkylphenol ethoxylates (APEOs) and the compliance with REACH Annex XVII Entry 46a restrictions on nonylphenol (˂100 mg/kg) eliminate a regulatory friction point for customers exporting finished goods to the European Union under the updated Toy Safety Directive 2009/48/EC when the adhesive layer is over-laminated with a decorative film in children’s furniture.
    Comparative Open Time and VOC Profile: Celvolit 1431 vs. Typical Adhesive-Grade VAE
    PropertyCelvolit 1431Standard VAE (54 % solids)Test Method
    VOC content (g/L)˂515–25ASTM D2369-20 Method B
    Open time (minutes)25–408–14Proprietary method, 50 % RH, PE substrate
    MFFT (°C)˂21–4ISO 2115:2000
    pH4.5–5.54.0–5.0ISO 976:2013
    Shear strength after 7 days (N/mm², beech/beech)3.6–4.22.8–3.5EN 205:2016
    Plasticizer contentNone detectedOften contains dibenzoate or DINCHGC-MS extraction
    The elevated open time does not equate to a universal one-to-one substitution for every VAE grade. In formulations requiring immediate green strength—such as high-speed paper tube winding where line speeds exceed 80 m/min—the delayed film formation of Celvolit 1431 results in a 30 % reduction in split resistance at the winding mandrel within the first 3 seconds of bond formation compared to a rapid-set, higher-Tg VAE with a −2 °C Tg. Therefore, operations with extremely short compression dwell times must either blend the emulsion with a faster-coalescing acrylic dispersion or incorporate 0.5–1.0 % of a polyvinyl alcohol borate complex to accelerate ionic crosslinking under the momentary nip pressure. The latter approach has been validated on a 1,500 mm wide rotary die-cut line processing 0.35 mm chipboard, where the addition of 0.7 % borate buffer restores acceptable tab-to-edge bond integrity without pushing the VOC level above 10 g/L. Finally, long-term durability in exterior exposure is influenced by the same stabilizer chemistry that extends open time. After 1,000 hours of QUV-B artificial weathering (ASTM G154-23 Cycle 1), the PVOH-rich interphase shows a 15–18 % reduction in elongation at break (film specimens of 0.25 mm thickness, tested per ISO 527-3:2018 at 500 mm/min) due to crosslinking of the hydroxyl sites. This stiffening is beneficial for holding power on vertical surfaces but must be considered when the bonded assembly experiences cyclic thermal movement greater than ±2 % linear displacement, where the modulus increase could transfer stress to the substrate and cause cracking in brittle tile or stone. Published data for this specific configuration on travertine-backed installations under −20 °C/+60 °C cycling per ETAG 004 is limited, indicating that full-scale testing remains advisable.