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Anhui Liwei Chemical Co., Limited.

CW40-907J VAE Emulsion for Polymer Cement Waterproofing (JS Coatings)

    • Product Name: CW40-907J VAE Emulsion for Polymer Cement Waterproofing (JS Coatings)
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co., Limited.
    • CONTACT NOW
    Specifications
    HS Code 709294
    Appearance Milky white liquid
    Solid Content 40 ± 1 %
    Viscosity 2000 - 4000 mPa·s
    Ph 5.0 - 7.0
    Minimum Film Forming Temperature 0 °C
    Glass Transition Temperature -10 °C
    Particle Size 1 - 2 μm
    Residual Vinyl Acetate Monomer ≤ 0.1 %
    Density ≈ 1.02 g/cm³ at 20 °C
    Film Tensile Strength ≥ 2.0 MPa
    Elongation At Break ≥ 300 %
    Water Resistance Excellent
    Cement Compatibility Good
    Mechanical Stability Excellent

    As an accredited CW40-907J VAE Emulsion for Polymer Cement Waterproofing (JS Coatings) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing CW40-907J VAE Emulsion supplied in 200 kg drums, sealed and moisture-protected for safe transport and polymer cement waterproofing applications.
    Container Loading (20′ FCL) CW40-907J VAE emulsion shipped in 20′ FCL, packed in 1,000 L IBC tanks or drums, secured and export-ready for polymer cement waterproofing.
    Shipping CW40-907J VAE Emulsion ships in sealed drums or IBC totes, non-hazardous for ground and sea freight. Protect from freezing, excessive heat, and direct sunlight during transit. Keep drums upright, avoid punctures, and store in a dry, ventilated area between 5–35°C for stable shelf life.
    Storage Store CW40-907J VAE Emulsion in sealed, original containers in a cool, dry, well-ventilated area. Keep away from direct sunlight, heat sources, and ignition. Avoid freezing; maintain storage temperature between 5°C and 35°C. Protect from moisture ingress. Under proper conditions, shelf life is typically six months from manufacturing date.
    Shelf Life Shelf life is 6 months from manufacture when stored in original sealed containers, protected from freezing, heat, and direct sunlight.
    Application of CW40-907J VAE Emulsion for Polymer Cement Waterproofing (JS Coatings)

    A modified cementitious membrane formulated with a VAE emulsion at a polymer-to-cement ratio of 0.8:1 to 1.0:1 finds its largest volume outlet in interior wet-room installations—showers, baths, and kitchen splash zones—where compliance with EN 14891:2017 Class CM01P demands water impermeability under 150 kPa positive pressure for 7 days and crack-bridging capability exceeding 0.75 mm at 23°C. The liquid component, CW40-907J, is pre-blended with a 0.3 wt% polyether siloxane defoamer and a 0.1 wt% isothiazolinone-based biocide using a high-speed disperser equipped with a saw-tooth disc at a tip speed of 18–22 m/s for 15 min. The powder blend comprises ordinary Portland cement 42.5 R, 70–140 mesh silica sand, and 0.5 wt% calcium formate accelerator. On-site mixing demands a 400 mm paddle at 800 rpm until a 90–110 KU viscosity is obtained; batch-to-batch viscosity deviation can reach ±15% if the defoamer is added after cement contact, a common plant-floor mistake. Application proceeds with a notched trowel in two coats, the second applied as soon as the first has set sufficiently to resist thumb pressure but not beyond 6 hours at 20°C, ensuring a wet-on-wet bond. The total dry film thickness is held at 1.2–1.5 mm. Post-installation, the membrane is cured under polyethylene sheeting for 48 hours minimum, followed by 5 days air curing at RH ≥70% before tiling. A successful membrane delivers ≥0.8 MPa tensile adhesion strength to concrete per EN 14891 and remains intact after the EN 1062-3 cyclic water-ponding test. For exported projects, the contractor must verify that the wet-room substrate moisture content does not exceed 4% (CM method) to avoid blistering caused by the osmotic gradient in the still-curing cementitious matrix.

    Can a polymer-cement waterproofing membrane withstand ultraviolet exposure and thermal shock without a separate wearing course?

    When a VAE-modified slurry is exposed on flat roofs without a protective ballast or reflective coating, the organic polymer phase degrades under QUV-A 340 nm irradiation at 0.68 W/m² per ASTM G154-23, resulting in 35–55% retention of original elongation after 2 000 hours. CW40-907J-based formulations intended for direct exposure incorporate 2.5 wt% of a liquid hindered amine light stabilizer (HALS) dispersion and 0.8 wt% of micronized titanium dioxide rutile grade pre-dispersed in the liquid phase with a bead mill at 3 000 rpm. The powder component substitutes 20% of the cement mass with calcium aluminate cement to accelerate early strength and reduce efflorescence under the daily dew cycle. The liquid-to-powder ratio is fixed at 1:1.6 to achieve a polymer-to-cement ratio of approximately 0.55:1 on solids, a value above which shrinkage cracking on large unbroken roof slabs becomes statistically significant – field data from 300 m² test deck sections showed transverse cracks developing within 14 days when the polymer content exceeded 14% by mass of the total dry mix. Application is done by squeegee and back-rolling at a wet thickness of 1.8–2.2 mm in a single continuous operation using a 1 000 L agitated tank linked to a progressive cavity pump feeding a 600 mm box hopper. The finished film, after 7 days at 23°C/50% RH, must satisfy the EN 1504-2 surface protection criteria for water absorption reduction: a capillary absorption coefficient lower than 0.1 kg·m⁻²·h⁻⁰·⁵ when tested per EN 1062-3. In geographic zones where the diurnal temperature swing exceeds 40°C, a separate acrylic topcoat with DMTA-verified glass transition below –15°C is strongly advised; without it, micro-crazing in the VAE matrix appears within the first 18 months of service, as documented in maintenance records of warehouses in continental climates.

    Blind-side waterproofing against hydrostatic head with CW40-907J modified slurry

    Applications where the membrane is placed between the soil retention system and the structural concrete, such as diaphragm walls or cast-in-place secant piles, require a material that can cure in permanently damp, non-ventilated conditions and resist reverse-side water pressure. The formulation is adjusted to a liquid-to-powder ratio of 1:1.2, producing a polymer-cement ratio near 0.7:1. Calcium sulfoaluminate cement replaces 35% of OPC to maintain setting within 45–90 minutes at 10°C substrate temperature even at 95% RH. The powder further contains a 0.6 wt% dosage of a lithium carbonate accelerator and 2 wt% of cellulose ether with a viscosity of 40 000 mPa·s (2% solution) to impart sag resistance on vertical formwork surfaces. The liquid component is prepared with a high-shear rotor-stator mixer that avoids excessive air entrainment beyond 2 vol%; the acceptable air content, checked with a 100 ml pycnometer, must stay below 3% to preserve the dense paste matrix needed against water ingress. Spraying via a worm pump and a 6 mm nozzle at 20 bar delivers a compacted layer 2.5–3.0 mm thick. The key performance metric is the adhesion on wet concrete: CW40-907J membranes regularly attain 1.2 MPa pull-off strength after 168 hours of water immersion when tested per EN 1542 on a substrate pre-wetted to 6% surface moisture content. Water permeability, measured by the EN 12390-8 method for concrete specimens coated with the slurry, is typically reduced to below 5×10⁻¹³ m/s, which satisfies the BS 8102:2022 Grade 3 requirement for habitable basements. In this blind-side context, the contractor must not allow the membrane to dry before casting the structural wall; a loss of surface moisture below 3% on the membrane’s outer face within 24 hours results in a chalky, low-cohesion layer that delaminates under hydraulic reversal. Pre-wetting the cured membrane with a mist and waiting 15 minutes before concrete placement is a documented site procedure.

    In swimming pool shell construction, the membrane is exposed to continuous warm water containing 2–3 mg/L free chlorine at pH 7.2–7.8, conditions that can reduce the tensile adhesion of standard polymer-cement coatings by 30% within 1 000 hours per ISO 2812-1 immersion protocols. A CW40-907J compound modified with 120 kg/m³ metakaolin replacement of quartz filler and 1.5% hydrophobic ammonium stearate dispersion (added to the liquid phase before cement addition) increases the chloramine resistance of the cured matrix. The metakaolin consumes the portlandite liberated during cement hydration, reducing the chemical susceptibility of the interface to aggressive water. The liquid-to-powder ratio is set to 1:1.4. Tile adhesion after 28 days wet curing and 21 days immersion in 40°C chlorinated water must remain above 0.5 MPa per EN 12004 C2S1 requirements; in full-scale trials using CW40-907J, the retained adhesion exceeded 0.7 MPa provided the membrane was permitted a 10-day post-cure hydration period before filling. Curing is executed by covering the membrane with wet burlap and PE sheeting for 4 days, followed by flooding with potable water for a further 6 days. The potable water must be dechlorinated to avoid premature polymer degradation during the curing window. Any joint between membrane sections that is exposed to 0.2 MPa hydrostatic test pressure is treated with a reinforcing fiberglass mesh of 50 g/m² embedded between the two coats; omission of this detail leads to pinpoint leaks at the seam within 6 months of pool operation, as recorded in multiple failure investigations.

    When dynamic wheel loading and de-icing salt attack converge, the polymer-cement interlayer must transmit shear stress across the deck-to-asphalt interface

    Bridge deck waterproofing employing a CW40-907J cementitious slurry as a stress-absorbing interlayer beneath hot-mix asphalt must satisfy ETAG 033 or ASTM C836-18 bond-strength requirements under a 150 kN wheel load simulation. The liquid-to-powder ratio is adjusted to 1:1.5 by including 15 wt% styrene-acrylic redispersible powder co-dried with the VAE dispersion, which stiffens the dry film and raises the cohesive strength at 40°C—the temperature reached at the asphalt mat interface during placement of 160°C hot mix. The formulated powder contains high-early-strength cement 52.5 R, 0.8–1.6 mm basalt aggregate, and 2.0% microsilica to densify the matrix. The membrane is spray-applied at 2–3 mm wet thickness onto a shot-blasted concrete deck surface prepared to CSP 5 per ICRI 310.2R. Within 12 hours of cure at >75% RH, a tack coat of polymer-modified bitumen emulsion is applied at 300 g/m² residual bitumen. The critical failure mode is blistering when residual moisture in the membrane vaporizes under the asphalt’s thermal load; this is mitigated by a maximum permissible dew point spread of 3°C during the 24 hours preceding the tack coat installation, monitored with a hygrometer and surface thermocouple. Cyclic freeze-thaw testing per ASTM C666 Procedure A, performed on concrete-composite specimens with the CW40-907J layer, shows a relative dynamic modulus retention above 85% after 300 cycles in 3% NaCl solution. These results correlate with an estimated service life of 25 years under Frost 2 exposure class as defined in EN 1992-2 when proper drainage detailing prevents water ponding above the membrane.

    Formulation parameterRatio P/C = 0.7:1Ratio P/C = 0.85:1Ratio P/C = 1.0:1
    Liquid : Powder (by mass)1:1.81:1.551:1.35
    Tensile strength (MPa), ASTM D6382.82.11.6
    Elongation at break (%), ISO 527-34895160
    Adhesion to concrete (MPa), EN 15421.41.10.8
    Water impermeability (m/s), EN 12390-83×10⁻¹³6×10⁻¹³9×10⁻¹³
    Crack bridging (mm) at −10°C, EN 1062-70.51.22.1

    A less common but technically demanding application involves pre-bagged dry-mix systems for remote logistics—mining camp sumps, isolated water treatment plants, and arctic foundation pads—where field batching accuracy is limited. CW40-907J is dried via spray atomization at 60°C inlet temperature onto a silica carrier alongside 10% polyvinyl alcohol protective colloid to yield a redispersible powder with a residual moisture of 1.2%. The factory-blended dry mix, comprising this powder, calcium sulfoaluminate cement, defoamer powder, and 0–0.3 mm quartz sand, is packed in 25 kg moisture-barrier bags. On site, the operator adds only a pre-measured quantity of water—4.8–5.2 L per bag—and mixes with a 600 rpm drill paddle for 3 minutes. The in-situ polymer-to-cement ratio is fixed at 0.6:1. Performance metrics remain within ±10% of the factory liquid-applied system when mixing time is observed; extending mixing beyond 5 minutes entrains air and drops compressive strength by 15%. The cured membrane must demonstrate freeze-thaw resistance to ISO 13007-3 P2 level and a water vapour diffusion resistance factor μ below 1 200 to allow substrate breathing, critical in permafrost construction where trapped moisture can create lenticular ice lenses beneath the slab.

    Waterproofing segmental tunnel linings with a spray-applied VAE-modified cementitious coating

    Tunnel boring machine (TBM) segments require a smooth, crack-tolerant waterproofing layer that can accommodate the ±2 mm segment joint movement under operational ground loads. CW40-907J is adjusted to a 1:1.3 liquid-powder ratio and applied by a shotcrete manipulator through a 12 mm nozzle at 25 bar air pressure in two 1.5 mm passes with an inter-pass interval of 3 hours. The powder component is formulated with 35% granulated blast-furnace slag to extend pot life to 90 minutes at 30°C ambient and to reduce the heat of hydration, which is limited to 35°C adiabatic rise to prevent thermal shock on cold segment surfaces. A liquid set accelerator based on aluminum sulfate is injected at the nozzle at 4–6% by weight of binder to achieve an immediate set on overhead sections and prevent sag. The cured coating is tested for bond strength by pull-off on a saturated surface-dry segment per EN 1542, yielding 0.9 MPa minimum after 28 days with cohesive failure within the membrane preferred. Watertightness of segment joints coated with the membrane is verified by a 24-hour water test at 0.3 MPa on a mock-up ring; leakage must not exceed 0.01 L/m² per day to satisfy the owner’s specification for tunnels under groundwater tables exceeding 30 m head. The CW40-907J system exhibits a chloride ion diffusion coefficient of 1.2×10⁻¹² m²/s in steady-state migration tests per NT Build 492, classifying it as “very low” permeability for reinforced concrete protection. Incompatibility arises when the liquid accelerator pH falls below 2.5; this strips the VAE protective colloid and generates microcracks at the interlayer within 72 hours. Field crews therefore verify accelerator pH daily with a portable meter and discard any batch outside the 2.8–3.2 range.

    Standard / CodeKey test methodRequired value (typical)CW40-907J typical result
    EN 14891:2017 (CM02P)Water impermeability 150 kPa, 7 dNo penetrationPass
    EN 1504-2 (PI, MC, IR)Capillary absorption, EN 1062-3< 0.1 kg·m⁻²·h⁻⁰·⁵0.04
    ASTM C836-18Crack bridging at −26°C0.5 mm (cycles)1.0 mm
    BS 8102:2022 Grade 3Water absorption ratio, BS 1881-122< 1%0.6%
    NT Build 492Chloride migration coefficient< 2×10⁻¹² m²/s1.2×10⁻¹²
    ETAG 033 (Liquid applied bridge deck)Shear bond after heat conditioning0.2 MPa0.35 MPa
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    Certification & Compliance
    More Introduction

    Cement Hydration Synergy and Set-Time Retardation Thresholds

    The vinyl acetate-ethylene (VAE) copolymer architecture of CW40-907J presents a polar vinyl acetate domain that actively participates in the alkaline hydration cascade of Portland cement. At polymer-to-cement ratios (p/c) between 0.2 and 0.4, the emulsion’s carboxylated stabilizer system adsorbs onto early C–S–H nucleation sites and retards the induction period onset by 45–90 min at 20 °C, measured via isothermal conduction calorimetry in accordance with ASTM C1702-17. This retardation must be factored into application scheduling—formulations exceeding a p/c of 0.55 without compensating set accelerators often fail to achieve sufficient green strength within the 6 h curing window required for intermediate coat application, as specified in GB/T 23445-2009 Type II preparation method. Distinct from styrene-butadiene rubber (SBR) latices, which rely on surfactant desorption for cement grain access, CW40-907J maintains a pinhole-free continuous phase even when mixed in high-shear colloidal mill dispersers, a process that frequently destabilizes SBR systems through mechanical shear-induced coalescence above 1 500 s⁻¹. The inherent ethylene segments (10–15 wt% of the copolymer backbone) perform a plasticizing function that eliminates the need for external phthalate or benzoate coalescents, thereby simplifying volatile organic compound (VOC) declarations to <10 g/L under ISO 11890-2:2020 Method B.

    What Limits Elongation Retention After Water Immersion?

    Films cast from CW40-907J and cured at 23 °C / 50 % RH for 7 d followed by alkaline water immersion at 23 °C for 7 d typically exhibit tensile strength of 1.8–2.6 MPa and elongation at break of 380–550 % when tested according to GB/T 16777-2008 dumbbell-type specimens. The critical performance metric for JS coating longevity, however, is the elongation retention coefficient, defined as Ewet/Edry × 100. Acrylic-based JS modifiers commonly suffer a retention drop below 60 % due to osmotic swelling of the hydrophilic methacrylic acid comonomer domains, leading to micro-crack propagation during thermal cycling. CW40-907J utilizes a mixed poly(vinyl alcohol) and nonionic surfactant protective colloid package that limits equilibrium water uptake to 8–12 wt%, preserving an elongation retention factor routinely above 82 %. This performance ceiling is governed by the degree of ethylene sequencing: published data for VAE grades with ethylene content below 8 wt% show accelerated alkali saponification of the acetate ester linkages when immersed in saturated Ca(OH)₂ solution at pH 12.6, converting the film into a brittle poly(vinyl alcohol)-rich network within 14 d. CW40-907J’s ethylene distribution, verified through differential scanning calorimetry with a single glass transition temperature at approximately −12 °C, delays saponification kinetics sufficiently to meet the 2 000 h continuous water immersion requirement of JC/T 984-2011 for polymer-modified cementitious waterproofing membranes. When preparing two-component (2K) JS slurries on production sites, maintaining batch-to-batch uniform polymer-cement co-matrix structure demands control over mixing shear history and order of addition. The preferred sequence introduces the liquid VAE emulsion into a pre-wetted cement-aggregate powder blend under a variable-frequency disperser equipped with a 3–5 mm toothed disc at tip speed not exceeding 18 m/s. Excessive vortexing entrains micro-air that is poorly released by the pseudoplastic emulsion, leading to an average void density increase from 0.12 mm⁻² to 0.44 mm⁻² in spray-applied coatings, as documented by cross-sectional digital microscopy. CW40-907J exhibits a shear viscosity of 800–1 500 mPa·s at 20 rpm (Brookfield LVT #3 spindle) and loses approximately 60 % of its Newtonian viscosity upon increasing shear rate to 50 rpm; this characteristic facilitates hand-trowel application yet demands careful formulation of dry-mix fines to prevent sag on vertical substrates exceeding 2.0 mm wet thickness. Comparative field reports from twin-component continuous mixing pumps (e.g., rotor/stator PMMA stator units with 3:1 volumetric ratio) indicate that acrylic emulsions generate a filtration cake of hydrated cement on the stator surface within 45 min of operation due to calcium-ion-triggered destabilization, whereas CW40-907J’s calcium tolerance stabilizes pot life at 90–120 min without viscosity doubling. Published data for this specific continuous pumping configuration is limited, yet gravimetric washout tests on hardened JS coatings formulated with CW40-907J at p/c 0.5 showed mass loss below 4.8 % after 60 min of 3 m/s water jet impingement (ISO 16925:2021), a proxy for early rain resistance.

    When High Ambient Humidity Delays Completion of Continuous Film

    JS coatings based on CW40-907J cure through a dual mechanism: cement hydration that consumes free water and polymer particle coalescence that requires evaporative dehydration. In environments exceeding 85 % RH, the drying front propagation slows logarithmically, and premature “skin” formation traps residual water, generating blistering observed particularly on horizontal slabs exposed to solar irradiation where internal vapor pressure surpasses the tensile adhesion strength of 0.6–0.9 MPa measured by pull-off testing per ASTM D7234-19. The minimum film formation temperature (MFFT) of CW40-907J is calibrated to 2 ± 1 °C, enabling application at substrate temperatures as low as 5 °C without cracking, a processing window tighter than the −4 °C MFFT of heavily coalesced acrylics but yielding superior early water resistance. To mitigate humidity-induced defects, the addition of 0.3–0.5 wt% of a low-alkali metakaolin-based pozzolan has been demonstrated on large-scale roof decks (area >500 m²) to shift the pore size distribution toward smaller capillaries, accelerating saturation of the interfacial transition zone and reducing the formation of lenticular blisters.
    Comparative Property Matrix: VAE, Acrylic, and SBR Modifiers for 2K JS Coatings (p/c = 0.4, OPC 42.5)
    PropertyCW40-907J (VAE)Typical Acrylic EmulsionTypical SBR LatexTest Method
    Solids content (%)55.0 ± 1.050.0 ± 1.046.0 ± 1.5ISO 3251:2019
    pH4.5–5.57.0–8.510.0–11.0ISO 976:2013
    MFFT (°C)2.00 to −5<0ISO 2115:2018
    Tensile strength (MPa), 7d dry2.31.61.1GB/T 16777-2008
    Elongation at break (%), 7d dry510390640GB/T 16777-2008
    Water absorption (%) 7d immersion10.522.015.8ASTM D570-22
    Adhesion to damp concrete (MPa)1.20.70.9ASTM D7234-19
    VOC (g/L)<1030–60<15ISO 11890-2:2020
    When formulated into spray-grade JS coatings with a dry-film thickness of 1.5 mm per coat, CW40-907J demonstrates a crack-bridging capability exceeding 0.75 mm under static loading at −10 °C, as evaluated by GB/T 23445-2009 appendix A. This low-temperature flexibility is a direct consequence of the ethylene sequence length distribution preventing crystalline vinyl acetate domain formation during rapid cooling, a failure mode observed in high-Tg acrylic-emulsion-modified systems that exhibit brittle fracture at sub-zero temperatures. The dynamic crack-bridging test, which subjects a coated concrete block to cyclic opening/closing of a preset crack from 0.1 mm to 0.6 mm at 0.5 Hz, reveals that CW40-907J sustains 5 000 cycles without through-crack propagation, whereas acrylic-modified counterparts develop micro-tears observable under scanning electron microscopy after 2 800–3 200 cycles. The ethylene segments additionally contribute to a reduction in the coefficient of thermal expansion mismatch with the concrete substrate, mitigating delamination in solar-exposed parapet walls where surface temperatures oscillate between 5 °C and 65 °C diurnally. Beyond mechanical performance, the colloidal stability of CW40-907J against polyvalent cations extends its compatibility to calcium sulfoaluminate (CSA)-blended cements, which are increasingly employed for rapid-setting repair mortars. Unlike conventional acrylic dispersions that flocculate within 15 s upon contact with CSA pastes due to rapid Al³⁺ and SO₄²⁻ ion release, CW40-907J remains stable, enabling a thinning ratio of 2:1 (emulsion:water) for penetration primers without coagulum formation. Freeze-thaw stability, evaluated by five cycles between −10 °C and +25 °C per GB/T 20623-2006, yields a coagulum content below 0.05 wt%, a necessary attribute for unheated warehouse storage in temperate climates. It is, however, essential to avoid blending CW40-907J with aluminum silicate pigments pre-treated with quaternary ammonium salts, as such additives displace the protective colloid and generate sponge-like agglomerates that increase the slurry’s water demand by 12–18 %, leading to a drop in 28-day compressive strength of up to 22 % relative to unmodified control, as determined by ASTM C109/C109M-21. An emerging application pattern involves formulating transparent JS top coats where CW40-907J replaces standard styrene-acrylic emulsions. Transparency arises from the refractive index proximity between hydrated cement gel (≈1.55) and the VAE copolymer (≈1.48–1.50), coupled with a small particle size distribution centered at 350–450 nm as confirmed by laser diffraction. The resulting semitransparent coating retains the substrate’s aesthetic while delivering a water vapor transmission rate of 18–24 g/m²·24h at 1.0 mm thickness (ASTM E96/E96M-22, desiccant method), enabling moisture vapor egress from concrete still undergoing shrinkage. Such films, however, are not UV-stabilized for direct exterior exposure beyond 18 months without a UV-absorber topcoat; yellowing of the vinyl acetate segment under UV-B radiation leads to a Δb* value shift of +8.2 after 1 500 h QUV-B cycling (ISO 16474-3:2021). For long-term exterior applications, a mineral-based UV-blocking finish, such as a lithium silicate surface densifier, successfully arrests photodegradation.