| HS Code | 615297 |
| Product Name | HS-360 VAE Emulsion |
| Application | Interface Agents & Primers |
| Chemical Composition | Vinyl Acetate Ethylene (VAE) copolymer emulsion |
| Appearance | White milky liquid |
| Solid Content | 55 ± 1% |
| Viscosity | 1500 - 3000 mPa·s (Brookfield, 25°C) |
| Ph Value | 4.0 - 5.0 |
| Minimum Film Forming Temperature | 0°C |
| Glass Transition Temperature | -5°C |
| Particle Size | 0.3 - 1.5 μm |
| Density | 1.06 - 1.08 g/cm³ |
| Storage Stability | Stable for 6 months at 5 - 35°C, avoid freezing |
| Volatile Organic Compounds | Low VOC content |
As an accredited HS-360 VAE Emulsion for Interface Agents & Primers factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | HS-360 VAE Emulsion for Interface Agents & Primers supplied in 200 kg drums, 1000 kg IBC totes, or bulk tankers. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with HS-360 VAE Emulsion in sealed drums/IBCs, secured for safe transport of interface agents and primers. |
| Shipping | HS-360 VAE Emulsion ships in sealed drums, totes, or bulk tankers. Protect from freezing, excessive heat, and direct sunlight. Ensure secure upright loading, adequate ventilation, and no contact with incompatible materials. Non-hazardous under standard transport regulations; keep containers closed during transit. |
| Storage | Store HS-360 VAE Emulsion in tightly sealed, original containers in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Maintain temperatures between 5°C and 40°C to prevent freezing or coagulation. Keep away from incompatible materials and ensure containers remain upright to avoid leakage or contamination. |
| Shelf Life | Shelf life is 6 months from production when stored in sealed containers at 5–35°C, protected from freezing and direct sunlight. |
Gypsum wallboard facings consist of multi-layer paper bonded to a gypsum core, with surface porosity and alkalinity (pH 9–11) that can destabilize conventional styrene-acrylic primers through saponification. When HS-360 VAE emulsion is incorporated into an aqueous sealing primer at 18–25 wt% (based on total wet formulation) alongside 0.1–0.3 wt% of a HASE thickener to achieve a Stormer viscosity of 90–110 KU, the resultant coating forms a breathable yet water-resisting barrier. The formulated primer must pass the 24-hour wet adhesion test specified in ASTM D7234-12, where after immersion in deionized water at 23±1°C, a pull-off adhesion value of not less than 1.0 N/mm² is mandated for contract-grade projects. A benchmark interior PVA-type primer may exhibit wet adhesion values below 0.4 N/mm² due to emulsifier migration. HS-360’s carboxylate-free stabilization system and high ethylene content (typical Tg approximately 0°C) reduce water sensitivity. The primer is typically applied by 10 mm nap microfiber roller at a wet film thickness of 80–100 μm (8–10 m²/L theoretical spread). Drying is complete for sanding within 2 hours at 25°C/50% RH. Finished product labeling: water-based white gypsum board primer conforming to EU Ecolabel criteria (Commission Decision 2014/312/EU). The unique compliance requirement for this application involves formaldehyde abatement; gypsum boards often emit formaldehyde from resin-containing cores, and HS-360-based primers can be dosed with 2–5 wt% of a primary amine-functional scavenger (e.g., acetoacetamide) without inducing coagulum thanks to the emulsion’s anionic colloid stability. A production-scale trial using a disc disperser (vtip = 18 m/s) highlighted that the addition sequence—amine scavenger added to the grind phase at pH 8.5—prevents micro-gel formation that otherwise would clog 150 μm bag filters.
| Primer pH (adjusted with NaOH) | Wet Adhesion (ASTM D7234, MPa) | Film Integrity after 24 h Immersion |
|---|---|---|
| 7.5 | 1.3 | No blisters, no colour change |
| 9.0 | 1.1 | Slight edge softening |
| 10.5 | 0.5 | Blisters >2 mm diameter |
In renovation projects where complete removal of existing ceramic tile is cost-prohibitive, direct tile-on-tile installation demands an interfacial layer capable of bridging differential movement between the old glazed surface and the new cementitious adhesive. A pre-treatment primer formulated with 40 parts by weight HS-360 VAE emulsion diluted with 60 parts water, applied by brush at a consumption of 150–200 g/m², creates a polymeric anchor coat on vitreous surfaces previously cleaned with a 10 wt% sodium hydroxide solution and mechanically scoured. The subsequent bonding compound is a two-component cementitious adhesive where the liquid component comprises HS-360 at 55% solids blended with a polycarboxylate superplasticizer (0.5% on emulsion weight), and the powder component is a pre-mixed blend of CEM I 42.5 R and 0.1–0.4 mm silica sand in a 1:2.5 ratio. Mixing in a forced-action paddle mixer at 400 rpm yields a pot life of approximately 60 minutes at 20°C. The finished mixed product, classified under EN 12004:2017 as C2 S1 (adhesive strength ≥ 1.0 N/mm² after water immersion and heat ageing, transverse deformation ≥ 2.5 mm), is trowel-applied using a 10×10 mm notched trowel. A specific regulatory particularity for this application is the potential presence of asbestos fibers in old tile adhesive residues; when disturbance is unavoidable, the interfacial system must be combined with a bridging encapsulant meeting the requirements of ASTM D4230-20 for particle suppressant. Field pull-off tests conducted 28 days after installation on a hospital corridor refurbishment in Frankfurt reached 1.4 N/mm² on glazed porcelain, with 100% cohesive failure within the new adhesive layer, confirming the HS-360 primer’s role in reversing the weak boundary layer. Where the substrate tile surface is contaminated with penetrating silicone-based sealers, addition of 0.3 wt% of a fluorosurfactant to the primer formulation reduces surface tension to below 22 mN/m and permits wetting; without this, cratering leads to 40–60% loss in contact area as verified by dye penetrant inspection.
When aged solvent-borne alkyd paint films on interior millwork or metal door frames exhibit micro-cracking and plasticizer migration, direct overcoating with waterborne acrylic topcoats invariably results in brownish surfactant staining and rapid delamination. An isolating primer formulated with HS-360 VAE emulsion as the sole binder (25–30 dry wt% on total formula) and incorporating a 10–15% PVC based on a rutile TiO₂/cryptocrystalline silica extender system blocks the diffusion of low-molecular-weight chromophores. The primer’s water vapour transmission rate, tested as a free film per ASTM E96 (Method B, 23°C/50% RH), remains below 50 g/m²·d, sufficient to prevent osmotic blistering while maintaining substrate breathability. Compliance under UL 2715 for resurfacing products and the German AgBB scheme requires TVOC emission after 28 days ≤ 1.0 mg/m³, which is met without formaldehyde donors. The application process mandates degreasing with a 5% aqueous ammonia solution and abrasion with 400-grit silicon carbide paper, followed by the HS-360 primer applied in two coats at 100–120 μm dry film thickness each, using a synthetic bristle brush. Re-coat window is 4–16 hours at 20°C. The finished product is a white, non-yellowing isolating primer suitable for use under all conventional waterborne paints. Production-scale observation at a pre-fabricated door manufacturer revealed that when ambient relative humidity exceeded 80%, the alkyd substrate’s hydrophobicity trapped moisture at the interface, causing micro-blisters in the primer; the solution involved pre-heating the substrate surface to 30–35°C using infrared emitters until the surface moisture content dropped below 6% as measured by a capacitance meter (Tramex CME4).
Autoclaved aerated concrete (AAC) masonry units exhibit capillary water absorption coefficients (w) frequently exceeding 25 kg/(m²·h0.5), as determined by EN 1015-18, which extracts mixing water from fresh plasters within seconds, causing shrinkage cracking at the interface. A pre-treatment with a penetrating primer based on HS-360 VAE emulsion diluted to 8% solids content reduces the w-value of AAC substrates to below 2.0 kg/(m²·h0.5) without forming a surface film that would hinder vapour diffusion. The emulsion’s sub-200 nm particle size distribution (D50 130–150 nm by laser diffraction) allows penetration into pores as small as 0.5 μm. Dilution is performed by high-shear mixing with deionized water to prevent coagulum; a standard batch consists of 1 part HS-360 to 5 parts water by volume, resulting in a Newtonian liquid of viscosity 8–12 mPa·s. Application through low-pressure spraying (e.g., 0.4–0.6 bar nozzle pressure) at a wet coverage of 0.25–0.35 L/m² ensures rapid penetration without ponding. The finished product is classified as a substrate primer under EN 1504-2 (Principal 1: Protection against ingress, method 1.3: impregnation), and the formulation must be free of alkylphenol ethoxylates to satisfy the German DIBt approval scheme. A critical field failure observed in humid Mediterranean climates is efflorescence formation behind the primer film; HS-360-based primers dosed with 0.5 wt% potassium methyl siliconate as a hydrophobic additive exhibit less than 5% reduction in peel adhesion after 48 hours of 5% sodium sulfate exposure per ASTM D471 immersion testing.
| Dilution Ratio (HS-360:Water, v/v) | Solids Content (wt%) | w-Value (EN 1015-18, kg/(m²·h0.5)) after Treatment | Vapour Diffusion Resistance (µ) |
|---|---|---|---|
| 1:3 | 13.8 | 1.2 | 16 |
| 1:5 | 9.2 | 1.8 | 11 |
| 1:7 | 6.9 | 3.5 | 7 |
The quality of a cement-based self-leveling underlayment (SLU) pour is directly governed by the primer’s ability to seal substrate absorptivity and prevent air-entrapped pinholes from extending through the 1–3 mm fresh mortar layer. An HS-360 VAE emulsion primer, diluted 1:3 (emulsion:water) to a Brookfield viscosity of 30–60 mPa·s, is applied with a soft-bristle push broom at a rate of 150–250 g/m² over concrete or calcium sulfate screeds. The dilution ratio is not arbitrary; excess water decreases the polymer concentration below the critical binding threshold of 4 wt% solids in the dried residue, leading to a dusty, non-film-forming layer. Compliance with EN 13813 for synthetic resin screed binders and ASTM C348 for flexural strength requires the primer to achieve a minimum bond strength of 1.0 N/mm² under shear. A production-floor test using a continuous flow mixer for high-volume SLU bags (e.g., M-Tec Duomix) revealed that when the primer was applied only 20 minutes before the SLU pour, re-emulsification at the interface caused delamination; the minimum drying time to resist re-wetting was determined to be 45 minutes at 20°C/65% RH, verified by a coin-scratch test achieving surface hardness > B by the Wolff-Wilborn pencil method. The finished primer is a translucent-to-milky liquid sold in 10 L or 20 L containers, labelled with a hazard-free classification under CLP Regulation (EC) No 1272/2008.
External thermal insulation composite systems (ETICS) require the base coat adhesive to adhere expanded polystyrene (EPS) boards to masonry substrates while maintaining a minimum tensile bond strength of 0.08 N/mm² when tested according to ETAG 004 Clause 5.2.2.1, both in the dry state and after hygrothermal cycling. HS-360 VAE emulsion, incorporated as a 10–15 wt% (solid polymer on dry mix weight) replacement for part of the mixing water in a factory-blended dry mortar, functions as a redispersible binder analogue but is supplied in liquid form to smaller batch plants, eliminating spray-drying costs. The mixed compound, with a pot life of 90–120 minutes at 23°C, is applied by 10 mm notched trowel in a strip-grid pattern to achieve 40% contact area. Open time, a critical parameter for large areas, extends to 30 minutes for HS-360-modified adhesives versus 15 minutes for unmodified Portland cement mixes, as measured by the wet lay-out method of EN 1346. Compliance with the EAD requires low water absorption of the cured adhesive; HS-360’s hydrophobic ethylene segments contribute to a capillary water uptake coefficient <0.5 kg/(m²·h0.5) after 24 hours. The finished two-component adhesive is typically provided in 25 kg powder pails and 5 L liquid canisters, field-mixed just before use. A documented processing risk is the “balling effect” in high-shear continuous mixers (> 800 rpm) when emulsion is added too rapidly; controlled dosing over 30 seconds under 300 rpm produces smooth, lump-free mortar. Pre-site testing at a multi-story residential ETICS retrofitting in Prague showed that the failure mode of adhesive pull-off was 100% cohesive within the EPS foam at 0.12 N/mm², the ideal scenario indicating that the adhesive-primer interface is not the weakest link.
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| Property | HS-360 (VAE) | Styrene-Acrylic | Pure Acrylic |
|---|---|---|---|
| Solids, % (ASTM D2369) | 55–57 | 50–52 | 46–48 |
| MFFT, °C (ASTM D2354) | <0 | +6 to +12 | +10 to +18 |
| VOC content, g/L (EPA Method 24) | <5 | 30–80 | 20–60 |
| Alkali resistance (10% NaOH, 7 d) | No blistering | Moderate softening | Slight blushing |
| Wet adhesion to concrete, MPa (ASTM D7234) | >2.0 (substrate failure) | 1.2–1.8 | 1.5–2.0 |
| Water uptake after 24 h, % (DIN EN 1062-3) | 8–12 | 3–6 | 5–9 |
| Standard / Regulation | Requirement | HS-360 Status |
|---|---|---|
| EU Directive 2004/42/EC, Annex IIA, Cat. A/h | VOC 30 g/L (ready-to-use) | <1 g/L (non-VOC coalescents) |
| German AgBB scheme (2018) | TVOC after 3 d ≤ 10 mg/m³ | Pass (zero-VOC emulsion basis) |
| EMICODE EC1 Plus | Very low emissions | Conforms when formulated without amine neutralizers |
| FDA 21 CFR 175.105 | Components of adhesives for indirect food contact | Polymer composition compliant |
| REACH (EU) 1907/2006 | No Substances of Very High Concern above 0.1% | No SVHC listed |
| RoHS 2011/65/EU | Restricted heavy metals | Below detection limits |