| HS Code | 405032 |
| Vinyl Acetate Content | 28 wt% |
| Density | 0.950 g/cm³ |
| Melt Flow Rate | 150 g/10 min (190°C/2.16 kg) |
| Melting Point | 66 °C |
| Vicat Softening Point | 44 °C |
| Tensile Strength At Break | 5.5 MPa |
| Elongation At Break | 700% |
| Shore A Hardness | 78 |
| Flexural Modulus | 22 MPa |
| Brittleness Temperature | -80 °C |
| Glass Transition Temperature | -34 °C |
As an accredited ELEVATE EM280AA Ethylene Vinyl Acetate Copolymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | ELEVATE EM280AA Ethylene Vinyl Acetate Copolymer is supplied as solid pellets in 25 kg multi-wall paper bags, palletized and shrink-wrapped for safe handling. |
| Container Loading (20′ FCL) | 20′ FCL: ELEVATE EM280AA Ethylene Vinyl Acetate Copolymer loaded in bags/pallets, secured for safe transport. |
| Shipping | ELEVATE EM280AA (Ethylene Vinyl Acetate Copolymer) ships as non-hazardous solid pellets in sealed bags or supersacks. Keep dry and away from excessive heat or ignition sources to prevent dust accumulation. Standard truck or container transport is suitable; no special restrictions apply, though proper handling gear is recommended. |
| Storage | Store ELEVATE EM280AA Ethylene Vinyl Acetate Copolymer in a cool, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep containers tightly sealed to prevent moisture contamination and avoid contact with strong oxidizing agents. Maintain moderate temperatures, ideally below 40°C, and ensure good housekeeping to prevent dust accumulation. |
| Shelf Life | Store in a cool, dry place. Shelf life is typically 2 years from date of manufacture if unopened. |
Hot-melt case-sealing lines operating above 200 m/min through slot-die applicators require a low-crystallinity EVA backbone with enough melt flow to fill heated hoses and starved gear pumps without charring; ELEVATE EM280AA is specified for this function at addition levels of 20 wt% to 35 wt% by total formulation mass. In a 150 L jacketed anchor-agitated mixer with nitrogen sparging at 160–180 °C, EM280AA is combined with C5/C9 hydrocarbon tackifier resins at 30–45 wt%, microcrystalline wax or Fischer-Tropsch wax at 15–30 wt%, and a hindered phenol/phosphite stabilizer package at 0.1–0.3 wt%; the mixer is run at 30–50 rpm until no undispersed EVA pellets remain visible in a hot glass draw, typically 60–90 min. Finished adhesive drawn through a heated 200 μm gap and measured by ASTM D3236-88(2021) at 180 °C generally falls within 350–1,200 mPa·s for pneumatic piston pumps and gear-driven drum unloaders, but site-specific applicator pressure limits may require the lower end of that range when nozzle orifices are below 0.3 mm. Field experience on high-speed corrugated lines shows that open time is set by wax/tackifier ratio rather than EVA loading; raising EM280AA from 20 wt% to 35 wt% increases cohesion and hot tack on wax-coated board but can increase stringing and transfer hose back-pressure. At addition above 35 wt%, viscosity gain and acetic acid evolution at hot nozzle tips become the most frequent cause of intermittent nozzle clogging unless drum unloader temperature is raised by 10–15 °C and the adhesive reservoir is blanketed with nitrogen. Pellet surface moisture above 0.05 wt% or melt temperature excursions above 210 °C accelerate thermal deacetylation, producing char in heated hoses; pre-drying at 60 °C for 4 h is specified when warehouse relative humidity exceeds 60%. Applicable regulatory benchmarks include FDA 21 CFR 177.1350 for EVA copolymers in food-contact adhesives, EU Regulation (EU) No 10/2011 Annex I for plastic food-contact materials, REACH Annex XVII, RoHS Directive 2011/65/EU for electrical/electronic assembly, and CONEG heavy-metal limits for packaging. Terminal product types include corrugated case and carton sealing, tray forming, rigid box side-seam bonding, bookbinding, paperboard-to-corrugated lamination, and pressure-sensitive label assembly.
| End use | EM280AA addition (wt%) | Tackifier resin (wt%) | Wax (wt%) | Application temperature (°C) | Viscosity reference method |
|---|---|---|---|---|---|
| Corrugated case sealing | 25–30 wt% | 40–45 wt% | 20–25 wt% | 160–170 °C | ASTM D3236-88(2021) |
| Paperboard tray forming | 20–25 wt% | 35–40 wt% | 25–30 wt% | 155–165 °C | ASTM D3236-88(2021) |
| Bookbinding side glue | 30–35 wt% | 30–40 wt% | 15–20 wt% | 170–180 °C | ISO 3219:2021 |
At addition levels between 10 wt% and 30 wt%, ELEVATE EM280AA is melt-blended into paraffin and Fischer-Tropsch wax compounds to raise softening point, flexural cracking resistance, and moisture-barrier retention on corrugated board. The process uses a vertical blend tank at 120–140 °C with an internal eductor or single-screw pellet feed into molten wax, followed by a high-shear rotor-stator mixer at 1,200–1,800 rpm; the homogeneous coating is applied through a slot die or multi-roll coater at 110–130 °C. Increasing EM280AA to 30 wt% raises low-shear viscosity from typical wax-only values below 50 mPa·s to 400–900 mPa·s at 130 °C, measured by ISO 3219:2021; this is beneficial for coating thickness control but above 30 wt% can produce curtain instability in air-knife coaters and high back-pressure in narrow slot dies. Below 10 wt%, the paraffin coating remains brittle under board flexing at cold-chain temperatures around 0–5 °C, and compression resistance after 48 h exposure at 90% relative humidity falls to levels comparable with unmodified wax. Because wax compounds are low in acid scavenger content, melt temperature is not permitted to exceed 160 °C during extended hold times; acetic acid by-products can corrode mild steel and copper piping if hold time exceeds 8 h at 150 °C. Compliance benchmarks for food packaging use include FDA 21 CFR 176.170 and FDA 21 CFR 176.180 for paper and paperboard components in contact with aqueous and fatty foods, EU Regulation (EU) No 10/2011, and BfR Recommendation XXXVI for paper-based food contact; for non-food export packaging, the material must meet REACH and RoHS. Terminal product types include corrugated case liners for fresh produce, frozen food cartons, cup stock and folding carton barrier coatings, and industrial wrap papers.
Co-rotating twin-screw compounding lines producing mono-pigment masterbatches at outputs from 800 kg/h to 2,500 kg/h achieve stable dispersion when ELEVATE EM280AA is used as carrier resin at 25 wt% to 50 wt% of the concentrate. Pigments and additives—carbon black, TiO₂, phthalocyanine blue, hindered amine light stabilizer packages—are dry-blended with EM280AA in a high-intensity mixer, then fed into the main hopper; filler loadings above 40 wt% are side-fed after the first mixing zones to avoid barrel overheating, and the screw configuration uses two to three kneading block arrays with downstream vacuum devolatilization at −0.08 MPa to remove low-level acetic acid and moisture. Melt temperature is held at 170–190 °C, and screen packs are specified at 125 μm to 250 μm depending on film or injection end-use; production-scale trials show that replacing a low-melt-index LDPE carrier with EM280AA under identical throughput reduces head pressure by 15–25 MPa at the screen changer but can lower final film dart impact if the finished film contains more than 6 wt% total vinyl acetate derived from the carrier. Because EVA can adhere to hot metal surfaces during pelletizing, the die face is kept below 210 °C and underwater pellet water temperature is controlled at 25–35 °C; die-hole freeze-off occurs when water temperature drops below 20 °C, and pellet agglomeration increases above 40 °C. Batch-to-batch variance in pigment moisture above 0.2 wt% produces pressure fluctuations and screen-pack plugging; pigments with free moisture above that threshold are pre-dried before high-intensity mixing. Regulatory compliance for masterbatch is dictated by the final article: food-contact masterbatch requires a pigment and additive slate meeting EU Regulation (EU) No 10/2011 Annex I and FDA 21 CFR 177.1350 if the masterbatch is used in EVA repeat-use food contact; REACH and RoHS apply to industrial film and injection molding concentrates. Terminal product types include blown film pigmented masterbatches, orchard and greenhouse film UV stabilizer concentrates, injection molding color concentrates for caps and crates, and conductive carbon black compounds for antistatic packaging.
When road binders require ring-and-ball softening point above 70 °C for heavy-duty asphalt mixtures and bridge deck waterproofing membranes, ELEVATE EM280AA is added at 3 wt% to 6 wt% by mass of bitumen. The production route involves heating penetration-grade bitumen to 175–185 °C in an agitated tank, adding EM280AA pellets through a screw feeder over 30–60 min while a high-shear rotor-stator mill imparts 1,500–2,500 rpm, then holding the blend at 180 °C for 60–120 min to complete swelling and dispersion. Data collected from pilot and production batches indicate that 5 wt% EM280AA increases ring-and-ball softening point by 10–25 °C when tested by EN 1427 and reduces penetration at 25 °C by 15–35 dmm under EN 1426, but low-temperature flexibility below −10 °C may decline if the base bitumen has high asphaltene content and if the addition exceeds 4 wt% without an aromatic process oil. Storage stability is a critical operational boundary: at addition above 6 wt%, phase separation can occur after unstirred storage at 180 °C, evidenced by a ring-and-ball softening point difference greater than 5 °C between top and bottom thirds when measured according to EN 13399. Heating above 200 °C is not permitted during PMB production because EVA decomposition releases acetic acid and causes viscosity loss; nitrogen blanketing and vent scrubbers are specified for production vessels. Compliance for road binders is governed by EN 14023 for polymer-modified bitumen and EN 13707 for paving-grade bitumen specifications; North American specifications may reference ASTM D5976 for polymer-modified asphalt cement. Terminal product types include porous asphalt and stone mastic asphalt (SMA), bridge deck waterproofing membranes, polymer-bitumen roofing membranes, self-adhesive cold-applied membranes, and airport runway joint sealants.
| Property and test method | Typical trend at 5 wt% EM280AA in penetration-grade bitumen | Specification/use benchmark |
|---|---|---|
| Ring-and-ball softening point, EN 1427 | Increase 10–25 °C | EN 14023 |
| Penetration at 25 °C, EN 1426 | Decrease 15–35 dmm | EN 14023 |
| Storage stability, EN 13399 | Top/bottom softening difference <5 °C after 72 h at 180 °C | EN 14023 |
Post-consumer polyethylene-rich regrind streams containing 10–20 wt% polypropylene contamination accept ELEVATE EM280AA at 5 wt% to 15 wt% as a non-reactive impact modifier and compatibilizer to restore notched impact energy and reduce delamination in injection molded articles. The regrind stream is dry-blended with EM280AA and a 0.1 wt% processing stabilizer before entering a co-rotating twin-screw extruder with L/D 40:1 at 180–210 °C; vacuum devolatilization at −0.08 MPa removes residual adhesive and paper label moisture from post-consumer flake. Field production experience on 2,500 kg/h lines shows that 10 wt% EM280AA lowers melt pressure at the screen changer by 10–18 MPa compared with unmodified mixed polyolefin recycle, but may reduce tensile yield stress by 10–20% when tested according to ISO 527-2:2012; the addition level is therefore selected based on whether the final part specification prioritizes impact or stiffness. Above 15 wt% EM280AA, mold ejection in high-cavitation tools can become erratic because the softer surface increases friction, and Vicat softening temperature measured by ISO 306:2022 may drop below 75 °C, restricting hot-fill packaging use. Published data for this specific configuration is limited, and compounders should validate Charpy notched impact energy according to ISO 179-1:2010 on production-scale specimens before fixing the addition level. Compliance for recycled-content compounds includes REACH Annex XVII, RoHS Directive 2011/65/EU, and for automotive interior parts, emission limits according to VDA 277 are typically specified by the tier supplier. Terminal product types include injection molded crates, material handling pallets, automotive wheel arch liners, pipe regrind compounds, outdoor furniture, and drainage chambers.
In EVA/PE crosslinked foam compounds, ELEVATE EM280AA is incorporated at 20 wt% to 40 wt%, where it contributes cell uniformity, shock absorption, and low-temperature flexibility after dicumyl peroxide cure. A two-stage process is typical: an internal mixer with tangential rotors compounds EVA, LDPE, azodicarbonamide blowing agent at 2.5–5 phr, dicumyl peroxide at 0.8–1.2 phr, zinc oxide at 1–3 phr, stearic acid at 0.5–1 phr, and calcium carbonate or talc filler at 0–30 phr at a drop temperature not exceeding 105 °C; the batch is then sheeted on a two-roll mill at 70–80 °C and compression molded at 175–180 °C under 15–20 MPa clamp pressure to trigger simultaneous crosslinking and foaming. The cure time is set by DCP half-life at 175 °C, approximately 5–7 min, and must be matched to mold thermal lag; thick sections above 20 mm require cooling under pressure to below 40 °C before demolding to prevent post-expansion and surface splitting. Above 40 wt% EM280AA, compression set improves but mold fouling increases due to acetate residues from the higher vinyl acetate content; below 20 wt%, the foam loses low-temperature flexibility and shows lower tear strength when evaluated by ISO 1798:2008. Moisture above 0.05 wt% in the compound produces pinholes and irregular cell collapse during expansion, so pre-drying at 60 °C for 4 h is specified before internal mixing when storage humidity exceeds 60%. Compliance for consumer and marine articles includes REACH Annex XVII, RoHS Directive 2011/65/EU, and for foam density and compression set, ASTM D3575-20 for flexible cellular materials made from olefin polymers; footwear midsoles are additionally evaluated by ISO 17707:2018 for flexing resistance and ISO 1798:2008 for tensile and elongation at break. Terminal product types include shoe midsoles, sandal footbeds, marine impact pads, fender profiles, expansion joint filler, kickboards, gym mats, and gaskets for HVAC access panels.
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ELEVATE EM280AA is an ethylene-vinyl acetate copolymer identified by the supplier as a 28 wt% vinyl acetate, antioxidant-stabilized grade with a melt mass-flow rate of 3.0 g/10 min when determined in accordance with ISO 1133-1 at 190 °C/2.16 kg. The product is differentiated from general-purpose low-density polyethylene by the insertion of vinyl acetate units along the polyethylene backbone. The grade designation encodes the nominal comonomer content, and the AA suffix denotes the presence of an antioxidant package intended for extended processing stability. Typical density reported under ISO 1183-1 is 0.951 g/cm³, and the material is supplied as standard cylindrical pellets.
The vinyl acetate units reduce crystallinity by interrupting ethylene sequence regularity. As a result, EM280AA exhibits a reduction in Shore A hardness to approximately 88 under ISO 868 and an increase in elongation at break to approximately 750 % under ISO 527-2 relative to an unmodified ethylene homopolymer. The loss of crystallinity lowers the peak melting temperature observed by differential scanning calorimetry under ISO 11357-3 to a range near 73 °C, which permits lower melt-processing temperatures and shorter cooling cycles in injection molding; however, the same structural feature reduces Vicat softening temperature to approximately 50 °C under ISO 306/A50, limiting continuous service under load at elevated temperatures.
| Property | Test method | Typical value |
|---|---|---|
| Vinyl acetate content | ASTM D5594 | 28 wt% |
| Melt mass-flow rate | ISO 1133-1 | 3.0 g/10 min at 190 °C/2.16 kg |
| Density | ISO 1183-1 | 0.951 g/cm³ |
| Shore A hardness | ISO 868 | 88 |
| Tensile strength at break | ISO 527-2 | 17 MPa |
| Elongation at break | ISO 527-2 | 750 % |
| Vicat softening temperature | ISO 306/A50 | 50 °C |
| Peak melting temperature | ISO 11357-3 | 73 °C |
Melt processing of EM280AA on single-screw extruders with an L/D ratio of 24:1 to 30:1 and a compression ratio of 2.5:1 to 3.5:1 is typically performed with a flat or slightly decreasing temperature profile from feed to die. Feed-zone set points should be maintained between 120 °C and 140 °C, while the metering zone and die are held in the range 170 °C to 190 °C. Extended operation above 220 °C accelerates deacetylation of the vinyl acetate segments, generating acetic acid and polyene sequences that deepen color and reduce melt viscosity stability. In injection molding, a melt temperature of 180 °C to 200 °C with a mold temperature of 20 °C to 40 °C and back pressure below 1.0 MPa is commonly used to avoid flashing and gate stringing.
Resin exposed to humid air with relative humidity above 60 % for more than 48 h should be dried at 70 °C for 4 h using desiccant air with a dew point of -40 °C. Although the copolymer is not highly hygroscopic, accumulated surface moisture can hydrolyze vinyl acetate groups during melting and produce surface defects on extruded profiles and sheet. The drying step is particularly critical when the product is compounded with hygroscopic halogenated flame retardants or with carbon black concentrates that introduce adsorbed water.
| Operation | Temperature range | Equipment or condition |
|---|---|---|
| Pre-drying | 70 °C | Desiccant-air dryer, 4 h, dew point -40 °C |
| Extrusion feed zone | 120 °C to 140 °C | Single-screw, L/D 24:1 to 30:1 |
| Extrusion metering and die | 170 °C to 190 °C | Compression ratio 2.5:1 to 3.5:1 |
| Injection-molding melt | 180 °C to 200 °C | Back pressure <1.0 MPa; mold 20 °C to 40 °C |
| Peroxide compounding stage | <125 °C to 130 °C | Low-shear mixing, short residence time |
| Crosslinking cure | 160 °C to 180 °C | Press cure, atmospheric or pressure |
In extrusion compounding, EM280AA is frequently used as a base resin for flexible profiles, injection-molded footwear components, protective padding, and crosslinked foam intermediates. The medium melt mass-flow rate of 3.0 g/10 min provides higher melt strength than high-MI EVA grades, which are typically preferred for hot-melt adhesives but lack sufficient dimensional stability in thick extrudates. Processing on twin-screw compounders with co-rotating screws should use medium shear screw elements rather than aggressive kneading blocks to avoid local temperature rise above the degradation threshold.
Compared with a lower vinyl acetate grade such as an 18 wt% EVA copolymer, EM280AA has lower crystallinity and a lower melting point. This difference produces measurable changes in mechanical response: Shore A hardness under ISO 868 is reduced from approximately 95 for the lower-VA grade to approximately 88 for EM280AA, while the elongation at break under ISO 527-2 is increased. The higher vinyl acetate content also improves the wetting and adhesion of the copolymer to polar substrates such as untreated polyurethane, epoxide-coated metal, and cellulosic fillers, but it simultaneously increases polarity and reduces resistance to non-polar solvents compared with LDPE.
In comparison with non-polar metallocene polyolefin elastomers, EM280AA introduces a polar vinyl acetate functionality that provides inherent adhesion without the use of maleic anhydride grafting. This property is utilized in flexible coextrusion tie layers and in adhesive-compound bases; however, the same polar ester group is susceptible to hydrolysis in hot, humid service and to loss of acetic acid at high temperature. Published data on long-term hydrolytic stability in this specific grade under aggressive 85 °C/85 % RH service are limited, and end-use testing is advised before specification.
Capillary rheometry under ISO 11443 is recommended for mold-filling simulation and for distinguishing EM280AA from high-MI EVA grades. Processors should not interchange the material with an EVA wax or a high-MI hot-melt grade solely on the basis of vinyl acetate content; melt viscosity and heat stability are controlled by both molecular architecture and stabilization.
Peroxide-initiated crosslinking of EM280AA is feasible with organic peroxides such as dicumyl peroxide, but the process window is constrained by the combination of the copolymer melting range and the peroxide decomposition kinetics. Dicumyl peroxide has a 10 h half-life temperature near 117 °C and a 1 h half-life temperature near 135 °C; at the melt temperatures required for shaping the copolymer, this leaves only a narrow margin between complete plastication and premature scorch. Compounds containing dicumyl peroxide and EM280AA should be processed below 125 °C to 130 °C in the mixing stage, then cured at 160 °C to 180 °C under pressure. Because vinyl acetate decomposition produces acetic acid, metal oxide acid acceptors may be included, but amine-based stabilizers and additives should be avoided because they form colored complexes and may interfere with the peroxide cure.
Foam expansion using azodicarbonamide blowing agents requires matching the decomposition temperature of the blowing agent to the crosslinking rate of the peroxide. Azodicarbonamide typically decomposes near 200 °C; formulations are therefore activated with zinc oxide or zinc stearate to lower the gas-release temperature into the 150 °C to 170 °C range where the melt strength from crosslinking is sufficient to contain gas pressure. Batch-to-batch variation in the vinyl acetate content of EM280AA is controlled by the supplier, but poorly dispersed peroxide or moisture can create local gel levels and surface defects in injection-molded foam components.
Vinyl acetate deacetylation follows a chain-elimination mechanism in which acetic acid is released and conjugated double-bond sequences are formed. Kinetic studies report that deacetylation accelerates rapidly above 220 °C, and the resulting conjugated polyene segments cause yellowing. Acid acceptors such as zinc stearate or calcium carbonate can neutralize released acetic acid in compounding; however, excessive loading above 5 phr increases density and reduces elongation at break under ISO 527-2.
Outdoor exposure of EVA can induce photo-oxidative degradation at the vinyl acetate segments. Weatherability testing under ISO 4892-2 cycle 1 with xenon arc at 340 nm should be used for applications requiring extended outdoor service. Hindered amine light stabilizers and UV absorbers are conventionally added; however, low-molecular-weight amines can interact with the vinyl acetate and cause color shifts, so additive selection should be confirmed with accelerated aging under ISO 188.
For food-contact applications, the suitability of ELEVATE EM280AA must be evaluated under FDA 21 CFR 177.1350 based on end-use film or profile thickness and food type; the supplier should be asked for a food-contact statement and migration data. Electrical and general-purpose articles fall under EU REACH and RoHS Directive 2011/65/EU, but producers must verify that downstream additives, colorants, and process aids meet the applicable restricted-substance limits.
Material stored in unopened original packaging below 40 °C and away from direct UV radiation retains a typical shelf life of 24 months; material beyond that period should be checked for melt flow stability and yellowing before use. Published data on specific long-term photostability of this grade under continuous xenon exposure are limited, and formulations requiring extended outdoor performance should be evaluated at end-use thickness and additive loading.